Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)

In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa­hedral geometry by six N atoms from three ethyl­enediamine ligands. The P atoms of the anions adopt a distorted tetra­hedral geometry. In the crystal, inter­molecular N—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Rafizadeh, Masoud, Saadati Moshtaghin, Hamid Reza, Amani, Vahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414105/
https://www.ncbi.nlm.nih.gov/pubmed/22904712
http://dx.doi.org/10.1107/S1600536812029984
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author Rafizadeh, Masoud
Saadati Moshtaghin, Hamid Reza
Amani, Vahid
author_facet Rafizadeh, Masoud
Saadati Moshtaghin, Hamid Reza
Amani, Vahid
author_sort Rafizadeh, Masoud
collection PubMed
description In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa­hedral geometry by six N atoms from three ethyl­enediamine ligands. The P atoms of the anions adopt a distorted tetra­hedral geometry. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network.
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spelling pubmed-34141052012-08-17 Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate) Rafizadeh, Masoud Saadati Moshtaghin, Hamid Reza Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa­hedral geometry by six N atoms from three ethyl­enediamine ligands. The P atoms of the anions adopt a distorted tetra­hedral geometry. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414105/ /pubmed/22904712 http://dx.doi.org/10.1107/S1600536812029984 Text en © Rafizadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rafizadeh, Masoud
Saadati Moshtaghin, Hamid Reza
Amani, Vahid
Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title_full Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title_fullStr Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title_full_unstemmed Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title_short Tris(ethyl­enediamine-κ(2) N,N′)nickel(II) bis­(dimethyl phosphate)
title_sort tris(ethyl­enediamine-κ(2) n,n′)nickel(ii) bis­(dimethyl phosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414105/
https://www.ncbi.nlm.nih.gov/pubmed/22904712
http://dx.doi.org/10.1107/S1600536812029984
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