The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)

The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), comprises two Fe(II) atoms octahedrally coordinated and bridged by two aqua O atoms that straddle a crystallographic inversion center, forming a quadrilateral core. The water ligands of the core are involved in hydrogen bonds with the tria...

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Detalles Bibliográficos
Autores principales: Liu, Yuan-Yuan, Yang, Pan, Ding, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414108/
https://www.ncbi.nlm.nih.gov/pubmed/22904715
http://dx.doi.org/10.1107/S160053681202613X
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author Liu, Yuan-Yuan
Yang, Pan
Ding, Bin
author_facet Liu, Yuan-Yuan
Yang, Pan
Ding, Bin
author_sort Liu, Yuan-Yuan
collection PubMed
description The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), comprises two Fe(II) atoms octahedrally coordinated and bridged by two aqua O atoms that straddle a crystallographic inversion center, forming a quadrilateral core. The water ligands of the core are involved in hydrogen bonds with the triazole N atoms of the organic mol­ecules, which generates a layer motif in the ab plane. There are π–π stacking inter­actions between benzene rings of 3.490 (6) Å, and between triazole rings of 3.543 (8) and 3.734 (7) Å in neighboring layers, forming a three-dimensional network.
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spelling pubmed-34141082012-08-17 The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3) Liu, Yuan-Yuan Yang, Pan Ding, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), comprises two Fe(II) atoms octahedrally coordinated and bridged by two aqua O atoms that straddle a crystallographic inversion center, forming a quadrilateral core. The water ligands of the core are involved in hydrogen bonds with the triazole N atoms of the organic mol­ecules, which generates a layer motif in the ab plane. There are π–π stacking inter­actions between benzene rings of 3.490 (6) Å, and between triazole rings of 3.543 (8) and 3.734 (7) Å in neighboring layers, forming a three-dimensional network. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414108/ /pubmed/22904715 http://dx.doi.org/10.1107/S160053681202613X Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yuan-Yuan
Yang, Pan
Ding, Bin
The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title_full The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title_fullStr The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title_full_unstemmed The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title_short The monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κN)iron(II)]–1,4-bis­(4H-1,2,4-triazol-4-yl)benzene (1/3)
title_sort monoclinic form of di-μ-aqua-bis­[diaqua­bis­(thio­cyanato-κn)iron(ii)]–1,4-bis­(4h-1,2,4-triazol-4-yl)benzene (1/3)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414108/
https://www.ncbi.nlm.nih.gov/pubmed/22904715
http://dx.doi.org/10.1107/S160053681202613X
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