Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc

The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter­molecular N—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autor principal: Geiger, David K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414110/
https://www.ncbi.nlm.nih.gov/pubmed/22904717
http://dx.doi.org/10.1107/S160053681203036X
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author Geiger, David K.
author_facet Geiger, David K.
author_sort Geiger, David K.
collection PubMed
description The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter­molecular N—H⋯O hydrogen bonds and intra­molecular N—H⋯O and N—H⋯N hydrogen bonding.
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spelling pubmed-34141102012-08-17 Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc Geiger, David K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter­molecular N—H⋯O hydrogen bonds and intra­molecular N—H⋯O and N—H⋯N hydrogen bonding. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414110/ /pubmed/22904717 http://dx.doi.org/10.1107/S160053681203036X Text en © David K. Geiger 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Geiger, David K.
Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title_full Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title_fullStr Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title_full_unstemmed Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title_short Bis(acetato-κO)bis­(4,5-dimethyl­benzene-1,2-diamine-κN)zinc
title_sort bis(acetato-κo)bis­(4,5-dimethyl­benzene-1,2-diamine-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414110/
https://www.ncbi.nlm.nih.gov/pubmed/22904717
http://dx.doi.org/10.1107/S160053681203036X
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