Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc

In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra­hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H⋯I and...

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Detalles Bibliográficos
Autores principales: Salehzadeh, Sadegh, Khalaj, Mehdi, Dehghanpour, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414111/
https://www.ncbi.nlm.nih.gov/pubmed/22904718
http://dx.doi.org/10.1107/S1600536812030486
Descripción
Sumario:In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra­hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H⋯I and C—H⋯O hydrogen bonds are observed, in addition to π–π stacking inter­actions, with a centroid–centroid distance of 3.72 (5) Å.

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