Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc

In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra­hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H⋯I and...

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Detalles Bibliográficos
Autores principales: Salehzadeh, Sadegh, Khalaj, Mehdi, Dehghanpour, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414111/
https://www.ncbi.nlm.nih.gov/pubmed/22904718
http://dx.doi.org/10.1107/S1600536812030486
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author Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
author_facet Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
author_sort Salehzadeh, Sadegh
collection PubMed
description In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra­hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H⋯I and C—H⋯O hydrogen bonds are observed, in addition to π–π stacking inter­actions, with a centroid–centroid distance of 3.72 (5) Å.
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spelling pubmed-34141112012-08-17 Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc Salehzadeh, Sadegh Khalaj, Mehdi Dehghanpour, Saeed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra­hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C—H⋯I and C—H⋯O hydrogen bonds are observed, in addition to π–π stacking inter­actions, with a centroid–centroid distance of 3.72 (5) Å. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414111/ /pubmed/22904718 http://dx.doi.org/10.1107/S1600536812030486 Text en © Salehzadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title_full Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title_fullStr Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title_full_unstemmed Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title_short Diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc
title_sort diiodido{2-[(4-meth­oxy­phen­yl)imino­meth­yl]pyridine-κ(2) n,n′}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414111/
https://www.ncbi.nlm.nih.gov/pubmed/22904718
http://dx.doi.org/10.1107/S1600536812030486
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