Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate

In the title compound, [CoCl(C(10)H(7)N(3)S)(2)]Cl·2H(2)O, the Co(II) atom is five-coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands and one Cl atom in a distorted trigonal–bipyramidal geometry. In the crystal, N—H⋯O and O—H⋯Cl hydrogen bonds and π–π inter...

Descripción completa

Detalles Bibliográficos
Autores principales: Shi, Zhan-Wang, Qin, Yan, Lin, Yan-Xia, Wu, Wei, Liang, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414112/
https://www.ncbi.nlm.nih.gov/pubmed/22904719
http://dx.doi.org/10.1107/S1600536812030371
_version_ 1782240153697255424
author Shi, Zhan-Wang
Qin, Yan
Lin, Yan-Xia
Wu, Wei
Liang, Peng
author_facet Shi, Zhan-Wang
Qin, Yan
Lin, Yan-Xia
Wu, Wei
Liang, Peng
author_sort Shi, Zhan-Wang
collection PubMed
description In the title compound, [CoCl(C(10)H(7)N(3)S)(2)]Cl·2H(2)O, the Co(II) atom is five-coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands and one Cl atom in a distorted trigonal–bipyramidal geometry. In the crystal, N—H⋯O and O—H⋯Cl hydrogen bonds and π–π inter­actions between the thia­zole, imidazole and benzene rings [centroid-to-centroid distances 3.546 (2), 3.683 (2) and 3.714 (2) Å] link the complex cations, chloride anions and uncoordinating water mol­ecules into a three-dimensional network.
format Online
Article
Text
id pubmed-3414112
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141122012-08-17 Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate Shi, Zhan-Wang Qin, Yan Lin, Yan-Xia Wu, Wei Liang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(C(10)H(7)N(3)S)(2)]Cl·2H(2)O, the Co(II) atom is five-coordinated by four N atoms from two chelating 2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands and one Cl atom in a distorted trigonal–bipyramidal geometry. In the crystal, N—H⋯O and O—H⋯Cl hydrogen bonds and π–π inter­actions between the thia­zole, imidazole and benzene rings [centroid-to-centroid distances 3.546 (2), 3.683 (2) and 3.714 (2) Å] link the complex cations, chloride anions and uncoordinating water mol­ecules into a three-dimensional network. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414112/ /pubmed/22904719 http://dx.doi.org/10.1107/S1600536812030371 Text en © Shi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Zhan-Wang
Qin, Yan
Lin, Yan-Xia
Wu, Wei
Liang, Peng
Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title_full Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title_fullStr Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title_full_unstemmed Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title_short Chloridobis[2-(1,3-thia­zol-4-yl-κN)-1H-benzimidazole-κN (3)]cobalt(II) chloride dihydrate
title_sort chloridobis[2-(1,3-thia­zol-4-yl-κn)-1h-benzimidazole-κn (3)]cobalt(ii) chloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414112/
https://www.ncbi.nlm.nih.gov/pubmed/22904719
http://dx.doi.org/10.1107/S1600536812030371
work_keys_str_mv AT shizhanwang chloridobis213thiazol4ylkn1hbenzimidazolekn3cobaltiichloridedihydrate
AT qinyan chloridobis213thiazol4ylkn1hbenzimidazolekn3cobaltiichloridedihydrate
AT linyanxia chloridobis213thiazol4ylkn1hbenzimidazolekn3cobaltiichloridedihydrate
AT wuwei chloridobis213thiazol4ylkn1hbenzimidazolekn3cobaltiichloridedihydrate
AT liangpeng chloridobis213thiazol4ylkn1hbenzimidazolekn3cobaltiichloridedihydrate

Ejemplares similares