[N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)

In the title compound, [HgBr(2)(C(22)H(28)N(2)O(6))], the Hg(II) ion is bonded to two Br(−) ions and two N atoms of the chelating Schiff base ligand in a distorted tetra­hedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the...

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Autores principales: Khalaji, Aliakbar Dehno, Dušek, Michal, Fejfarová, Karla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414113/
https://www.ncbi.nlm.nih.gov/pubmed/22904720
http://dx.doi.org/10.1107/S1600536812030577
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author Khalaji, Aliakbar Dehno
Dušek, Michal
Fejfarová, Karla
author_facet Khalaji, Aliakbar Dehno
Dušek, Michal
Fejfarová, Karla
author_sort Khalaji, Aliakbar Dehno
collection PubMed
description In the title compound, [HgBr(2)(C(22)H(28)N(2)O(6))], the Hg(II) ion is bonded to two Br(−) ions and two N atoms of the chelating Schiff base ligand in a distorted tetra­hedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N′-dimethyl­ethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208 (3).
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spelling pubmed-34141132012-08-17 [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II) Khalaji, Aliakbar Dehno Dušek, Michal Fejfarová, Karla Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgBr(2)(C(22)H(28)N(2)O(6))], the Hg(II) ion is bonded to two Br(−) ions and two N atoms of the chelating Schiff base ligand in a distorted tetra­hedral geometry. The Schiff base ligand adopts an E,E conformation. The dihedral angle between the planes of the two halves of the central N,N′-dimethyl­ethylenediamine part of the ligand is 2.3 (11)°. The crystal studied was twinned by pseudomerohedry [twin law (0-10/-100/00-1)]; the contribution of the minor twin component refined to 0.208 (3). International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414113/ /pubmed/22904720 http://dx.doi.org/10.1107/S1600536812030577 Text en © Khalaji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalaji, Aliakbar Dehno
Dušek, Michal
Fejfarová, Karla
[N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title_full [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title_fullStr [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title_full_unstemmed [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title_short [N,N′-Bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) N,N′]dibromido­mercury(II)
title_sort [n,n′-bis(2,3,4-trimeth­oxy­benzyl­idene)­ethane-1,2-diamine-κ(2) n,n′]dibromido­mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414113/
https://www.ncbi.nlm.nih.gov/pubmed/22904720
http://dx.doi.org/10.1107/S1600536812030577
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