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trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN (3))copper(II)
In the title compound, [Cu(NO(3))(2)(C(5)H(6)N(2))(4)], the Cu(II) ion is located on an inversion centre. It features a Jahn–Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial posi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414114/ https://www.ncbi.nlm.nih.gov/pubmed/22904721 http://dx.doi.org/10.1107/S1600536812030607 |
| _version_ | 1782240154156531712 |
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| author | Şen, Fatih Şahin, Ramazan Andaç, Ömer Taş, Murat |
| author_facet | Şen, Fatih Şahin, Ramazan Andaç, Ömer Taş, Murat |
| author_sort | Şen, Fatih |
| collection | PubMed |
| description | In the title compound, [Cu(NO(3))(2)(C(5)H(6)N(2))(4)], the Cu(II) ion is located on an inversion centre. It features a Jahn–Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6):0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3414114 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141142012-08-17 trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN (3))copper(II) Şen, Fatih Şahin, Ramazan Andaç, Ömer Taş, Murat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(5)H(6)N(2))(4)], the Cu(II) ion is located on an inversion centre. It features a Jahn–Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6):0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414114/ /pubmed/22904721 http://dx.doi.org/10.1107/S1600536812030607 Text en © Şen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Şen, Fatih Şahin, Ramazan Andaç, Ömer Taş, Murat trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN (3))copper(II) |
| title |
trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN
(3))copper(II) |
| title_full |
trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN
(3))copper(II) |
| title_fullStr |
trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN
(3))copper(II) |
| title_full_unstemmed |
trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN
(3))copper(II) |
| title_short |
trans-Bis(nitrato-κO)tetrakis(1-vinyl-1H-imidazole-κN
(3))copper(II) |
| title_sort | trans-bis(nitrato-κo)tetrakis(1-vinyl-1h-imidazole-κn
(3))copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414114/ https://www.ncbi.nlm.nih.gov/pubmed/22904721 http://dx.doi.org/10.1107/S1600536812030607 |
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