Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]

In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion formed by two edge-sharing GeS(4) tetra­hedral units lies around an inversion centre. The average terminal and bridging Ge—S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and or...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Nian-Nian, Xu, Chao, Duan, Taike, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414115/
https://www.ncbi.nlm.nih.gov/pubmed/22904722
http://dx.doi.org/10.1107/S1600536812030334
_version_ 1782240154381975552
author Wang, Nian-Nian
Xu, Chao
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
author_facet Wang, Nian-Nian
Xu, Chao
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
author_sort Wang, Nian-Nian
collection PubMed
description In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion formed by two edge-sharing GeS(4) tetra­hedral units lies around an inversion centre. The average terminal and bridging Ge—S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N—H⋯S hydrogen bonds.
format Online
Article
Text
id pubmed-3414115
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141152012-08-17 Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)] Wang, Nian-Nian Xu, Chao Duan, Taike Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion formed by two edge-sharing GeS(4) tetra­hedral units lies around an inversion centre. The average terminal and bridging Ge—S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N—H⋯S hydrogen bonds. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414115/ /pubmed/22904722 http://dx.doi.org/10.1107/S1600536812030334 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Nian-Nian
Xu, Chao
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title_full Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title_fullStr Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title_full_unstemmed Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title_short Bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(IV)]
title_sort bis[3,3′-(piperazine-1,4-di­yl)­dipropan­aminium] di-μ(2)-sulfido-bis­[disulfido­german­ate(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414115/
https://www.ncbi.nlm.nih.gov/pubmed/22904722
http://dx.doi.org/10.1107/S1600536812030334
work_keys_str_mv AT wangniannian bis33piperazine14diyldipropanaminiumdim2sulfidobisdisulfidogermanateiv
AT xuchao bis33piperazine14diyldipropanaminiumdim2sulfidobisdisulfidogermanateiv
AT duantaike bis33piperazine14diyldipropanaminiumdim2sulfidobisdisulfidogermanateiv
AT chenqun bis33piperazine14diyldipropanaminiumdim2sulfidobisdisulfidogermanateiv
AT zhangqianfeng bis33piperazine14diyldipropanaminiumdim2sulfidobisdisulfidogermanateiv

Ejemplares similares