Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate

The title compound, K(+)·C(8)H(8)BF(3)N(3) (−), is a salt containing the chiral organic trifluorido­borate anion. The organic anions and potassium cations are tightly bound to each other by the coordination K—F [2.654 (3)–3.102 (3) Å] and K—N [2.951 (4)–3.338 (4) Å] inter­actions. Thus, the potassiu...

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Detalles Bibliográficos
Autores principales: Lejon, Tore, Gorovoy, Alexey S., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414117/
https://www.ncbi.nlm.nih.gov/pubmed/22904724
http://dx.doi.org/10.1107/S1600536812030085
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author Lejon, Tore
Gorovoy, Alexey S.
Khrustalev, Victor N.
author_facet Lejon, Tore
Gorovoy, Alexey S.
Khrustalev, Victor N.
author_sort Lejon, Tore
collection PubMed
description The title compound, K(+)·C(8)H(8)BF(3)N(3) (−), is a salt containing the chiral organic trifluorido­borate anion. The organic anions and potassium cations are tightly bound to each other by the coordination K—F [2.654 (3)–3.102 (3) Å] and K—N [2.951 (4)–3.338 (4) Å] inter­actions. Thus, the potassium cation adopts a nine-vertex coordination polyhedron, which can be described as a distorted monocapped tetra­gonal anti­prism. In the crystal, the organic anions and potassium cations form layers parallel to (001). Weak C—H⋯π inter­actions between neighbouring phenyl rings further stabilize the crystal.
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spelling pubmed-34141172012-08-17 Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate Lejon, Tore Gorovoy, Alexey S. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, K(+)·C(8)H(8)BF(3)N(3) (−), is a salt containing the chiral organic trifluorido­borate anion. The organic anions and potassium cations are tightly bound to each other by the coordination K—F [2.654 (3)–3.102 (3) Å] and K—N [2.951 (4)–3.338 (4) Å] inter­actions. Thus, the potassium cation adopts a nine-vertex coordination polyhedron, which can be described as a distorted monocapped tetra­gonal anti­prism. In the crystal, the organic anions and potassium cations form layers parallel to (001). Weak C—H⋯π inter­actions between neighbouring phenyl rings further stabilize the crystal. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414117/ /pubmed/22904724 http://dx.doi.org/10.1107/S1600536812030085 Text en © Lejon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lejon, Tore
Gorovoy, Alexey S.
Khrustalev, Victor N.
Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title_full Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title_fullStr Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title_full_unstemmed Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title_short Potassium [(1S)-1-azido-2-phenyl­eth­yl]trifluorido­borate
title_sort potassium [(1s)-1-azido-2-phenyl­eth­yl]trifluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414117/
https://www.ncbi.nlm.nih.gov/pubmed/22904724
http://dx.doi.org/10.1107/S1600536812030085
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