Cargando…
catena-Poly[[[bis(thiourea-κS)cadmium]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N] dihydrate]
The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thiocyanate groups. Two solvent molecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coord...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414119/ https://www.ncbi.nlm.nih.gov/pubmed/22904726 http://dx.doi.org/10.1107/S1600536812030267 |
Sumario: | The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thiocyanate groups. Two solvent molecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coordinated in a distorted octahedral fashion by two N and two S atoms from four thiocyanate ligands and by two S atoms from two thiourea molecules. Weak O—H⋯S, N—H⋯O and N—H⋯N interactions reinforce the structure. |
---|