catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]

The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thio­cyanate groups. Two solvent mol­ecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coord...

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Detalles Bibliográficos
Autores principales: Mietlarek-Kropidłowska, Anna, Chojnacki, Jaroslaw
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414119/
https://www.ncbi.nlm.nih.gov/pubmed/22904726
http://dx.doi.org/10.1107/S1600536812030267
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author Mietlarek-Kropidłowska, Anna
Chojnacki, Jaroslaw
author_facet Mietlarek-Kropidłowska, Anna
Chojnacki, Jaroslaw
author_sort Mietlarek-Kropidłowska, Anna
collection PubMed
description The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thio­cyanate groups. Two solvent mol­ecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coordinated in a distorted octa­hedral fashion by two N and two S atoms from four thio­cyanate ligands and by two S atoms from two thio­urea mol­ecules. Weak O—H⋯S, N—H⋯O and N—H⋯N inter­actions reinforce the structure.
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spelling pubmed-34141192012-08-17 catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate] Mietlarek-Kropidłowska, Anna Chojnacki, Jaroslaw Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thio­cyanate groups. Two solvent mol­ecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coordinated in a distorted octa­hedral fashion by two N and two S atoms from four thio­cyanate ligands and by two S atoms from two thio­urea mol­ecules. Weak O—H⋯S, N—H⋯O and N—H⋯N inter­actions reinforce the structure. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414119/ /pubmed/22904726 http://dx.doi.org/10.1107/S1600536812030267 Text en © Mietlarek-Kropidłowska and Chojnacki 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mietlarek-Kropidłowska, Anna
Chojnacki, Jaroslaw
catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title_full catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title_fullStr catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title_full_unstemmed catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title_short catena-Poly[[[bis­(thio­urea-κS)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] dihydrate]
title_sort catena-poly[[[bis­(thio­urea-κs)cadmium]-di-μ-thio­cyanato-κ(2) n:s;κ(2) s:n] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414119/
https://www.ncbi.nlm.nih.gov/pubmed/22904726
http://dx.doi.org/10.1107/S1600536812030267
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