(N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)

The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo­octa­diene ligand as well as a monoanionic bidentate benzoyl­thio­ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the...

Descripción completa

Detalles Bibliográficos
Autores principales: Warsink, Stefan, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414120/
https://www.ncbi.nlm.nih.gov/pubmed/22904727
http://dx.doi.org/10.1107/S1600536812029753
_version_ 1782240155566866432
author Warsink, Stefan
Roodt, Andreas
author_facet Warsink, Stefan
Roodt, Andreas
author_sort Warsink, Stefan
collection PubMed
description The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo­octa­diene ligand as well as a monoanionic bidentate benzoyl­thio­ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo­octa­diene ligand do not deviate by more than 0.031 Å from their least mean-squares plane.
format Online
Article
Text
id pubmed-3414120
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141202012-08-17 (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I) Warsink, Stefan Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo­octa­diene ligand as well as a monoanionic bidentate benzoyl­thio­ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo­octa­diene ligand do not deviate by more than 0.031 Å from their least mean-squares plane. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414120/ /pubmed/22904727 http://dx.doi.org/10.1107/S1600536812029753 Text en © Warsink and Roodt 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warsink, Stefan
Roodt, Andreas
(N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title_full (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title_fullStr (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title_full_unstemmed (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title_short (N-Benzoyl-N′,N′-diphenyl­thio­ureato-κ(2) S,O)(η(4)-cyclo­octa-1,5-diene)rhodium(I)
title_sort (n-benzoyl-n′,n′-diphenyl­thio­ureato-κ(2) s,o)(η(4)-cyclo­octa-1,5-diene)rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414120/
https://www.ncbi.nlm.nih.gov/pubmed/22904727
http://dx.doi.org/10.1107/S1600536812029753
work_keys_str_mv AT warsinkstefan nbenzoylnndiphenylthioureatok2soē4cycloocta15dienerhodiumi
AT roodtandreas nbenzoylnndiphenylthioureatok2soē4cycloocta15dienerhodiumi

Ejemplares similares