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Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)

The structure of the centrosymmetric title complex, [Cu(C(5)H(9)O(2))(2)(C(6)H(7)NO)(2)], has the Cu(II) atom on a centre of inversion. The Cu(II) atom is six-coordinate with a distorted octa­hedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two c...

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Detalles Bibliográficos
Autores principales: Shaikh, M. Mobin, Mishra, Veenu, Ram, Priti, Birla, Anil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414121/
https://www.ncbi.nlm.nih.gov/pubmed/22904728
http://dx.doi.org/10.1107/S1600536812030917
Descripción
Sumario:The structure of the centrosymmetric title complex, [Cu(C(5)H(9)O(2))(2)(C(6)H(7)NO)(2)], has the Cu(II) atom on a centre of inversion. The Cu(II) atom is six-coordinate with a distorted octa­hedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxyl­ate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by inter­molecular C—H⋯O and intra­molecular O—H⋯O hydrogen-bond inter­actions.