Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)

The structure of the centrosymmetric title complex, [Cu(C(5)H(9)O(2))(2)(C(6)H(7)NO)(2)], has the Cu(II) atom on a centre of inversion. The Cu(II) atom is six-coordinate with a distorted octa­hedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two c...

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Detalles Bibliográficos
Autores principales: Shaikh, M. Mobin, Mishra, Veenu, Ram, Priti, Birla, Anil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414121/
https://www.ncbi.nlm.nih.gov/pubmed/22904728
http://dx.doi.org/10.1107/S1600536812030917
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author Shaikh, M. Mobin
Mishra, Veenu
Ram, Priti
Birla, Anil
author_facet Shaikh, M. Mobin
Mishra, Veenu
Ram, Priti
Birla, Anil
author_sort Shaikh, M. Mobin
collection PubMed
description The structure of the centrosymmetric title complex, [Cu(C(5)H(9)O(2))(2)(C(6)H(7)NO)(2)], has the Cu(II) atom on a centre of inversion. The Cu(II) atom is six-coordinate with a distorted octa­hedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxyl­ate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by inter­molecular C—H⋯O and intra­molecular O—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-34141212012-08-17 Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II) Shaikh, M. Mobin Mishra, Veenu Ram, Priti Birla, Anil Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the centrosymmetric title complex, [Cu(C(5)H(9)O(2))(2)(C(6)H(7)NO)(2)], has the Cu(II) atom on a centre of inversion. The Cu(II) atom is six-coordinate with a distorted octa­hedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxyl­ate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by inter­molecular C—H⋯O and intra­molecular O—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414121/ /pubmed/22904728 http://dx.doi.org/10.1107/S1600536812030917 Text en © Shaikh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shaikh, M. Mobin
Mishra, Veenu
Ram, Priti
Birla, Anil
Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title_full Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title_fullStr Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title_full_unstemmed Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title_short Bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) N,O](pivalato-κO)copper(II)
title_sort bis[2-(2-hy­droxy­meth­yl)pyridine-κ(2) n,o](pivalato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414121/
https://www.ncbi.nlm.nih.gov/pubmed/22904728
http://dx.doi.org/10.1107/S1600536812030917
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