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Propane-1,3-diammonium dichromate(VI)
The title compound, (C(3)H(12)N(2))[Cr(2)O(7)], consists of a discrete dichromate anion with an eclipsed conformation and a propane-1,3-diammonium cation. Both kinds of ions have a mirror plane passing through the bridging O atom and the central methylene C atom of the Cr(2)O(7) (2−) and C(3)H(12)N...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414122/ https://www.ncbi.nlm.nih.gov/pubmed/22904729 http://dx.doi.org/10.1107/S1600536812031042 |
Sumario: | The title compound, (C(3)H(12)N(2))[Cr(2)O(7)], consists of a discrete dichromate anion with an eclipsed conformation and a propane-1,3-diammonium cation. Both kinds of ions have a mirror plane passing through the bridging O atom and the central methylene C atom of the Cr(2)O(7) (2−) and C(3)H(12)N(2) (2+) moieties, respectively. Anions and cations are alternately stacked to form columns parallel to the b axis. Ions are linked by intra- and inter-column hydrogen bonds of types N—H⋯O and C—H⋯O, involving O atoms of the dichromate anions as acceptors, and ammonium or methylene groups as donors. |
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