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Propane-1,3-diammonium dichromate(VI)

The title compound, (C(3)H(12)N(2))[Cr(2)O(7)], consists of a discrete dichromate anion with an eclipsed conformation and a propane-1,3-diammonium cation. Both kinds of ions have a mirror plane passing through the bridging O atom and the central methyl­ene C atom of the Cr(2)O(7) (2−) and C(3)H(12)N...

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Detalles Bibliográficos
Autores principales: Trabelsi, Sonia, Marouani, Houda, Al-Deyab, Salem S., Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414122/
https://www.ncbi.nlm.nih.gov/pubmed/22904729
http://dx.doi.org/10.1107/S1600536812031042
Descripción
Sumario:The title compound, (C(3)H(12)N(2))[Cr(2)O(7)], consists of a discrete dichromate anion with an eclipsed conformation and a propane-1,3-diammonium cation. Both kinds of ions have a mirror plane passing through the bridging O atom and the central methyl­ene C atom of the Cr(2)O(7) (2−) and C(3)H(12)N(2) (2+) moieties, respectively. Anions and cations are alternately stacked to form columns parallel to the b axis. Ions are linked by intra- and inter-column hydrogen bonds of types N—H⋯O and C—H⋯O, involving O atoms of the dichromate anions as acceptors, and ammonium or methyl­ene groups as donors.