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Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3) O (1),O (1′):O (3)]nickel(II)]
In the title compound, [Ni(C(20)H(13)O(5)P)(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) cation is coordinated by three O atoms from two 5-(diphenylphosphinoyl)isophthalate anions, two N atoms from two 1,2-bis(pyridin-4-yl)ethene ligands and one water molecule in a distorted octahedral geometry. Both...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414124/ https://www.ncbi.nlm.nih.gov/pubmed/22904731 http://dx.doi.org/10.1107/S1600536812031108 |
| _version_ | 1782240156449767424 |
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| author | Zhang, Peng Liu, Yu-Jie Li, Kai-Hui Yang, Guang-Rui Mei, Chong-Zhen |
| author_facet | Zhang, Peng Liu, Yu-Jie Li, Kai-Hui Yang, Guang-Rui Mei, Chong-Zhen |
| author_sort | Zhang, Peng |
| collection | PubMed |
| description | In the title compound, [Ni(C(20)H(13)O(5)P)(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) cation is coordinated by three O atoms from two 5-(diphenylphosphinoyl)isophthalate anions, two N atoms from two 1,2-bis(pyridin-4-yl)ethene ligands and one water molecule in a distorted octahedral geometry. Both 1,2-bis(pyridin-4-yl)ethene and 5-(diphenylphosphinoyl)isophthalate bridge the Ni(II) cations to form polymeric layers parallel to (001). In the crystal, O—H⋯O hydrogen bonding links layers into a three-dimensional supramolecular structure. |
| format | Online Article Text |
| id | pubmed-3414124 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141242012-08-17 Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3) O (1),O (1′):O (3)]nickel(II)] Zhang, Peng Liu, Yu-Jie Li, Kai-Hui Yang, Guang-Rui Mei, Chong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(20)H(13)O(5)P)(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) cation is coordinated by three O atoms from two 5-(diphenylphosphinoyl)isophthalate anions, two N atoms from two 1,2-bis(pyridin-4-yl)ethene ligands and one water molecule in a distorted octahedral geometry. Both 1,2-bis(pyridin-4-yl)ethene and 5-(diphenylphosphinoyl)isophthalate bridge the Ni(II) cations to form polymeric layers parallel to (001). In the crystal, O—H⋯O hydrogen bonding links layers into a three-dimensional supramolecular structure. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414124/ /pubmed/22904731 http://dx.doi.org/10.1107/S1600536812031108 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Peng Liu, Yu-Jie Li, Kai-Hui Yang, Guang-Rui Mei, Chong-Zhen Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2) N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3) O (1),O (1′):O (3)]nickel(II)] |
| title | Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
O
(1),O
(1′):O
(3)]nickel(II)] |
| title_full | Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
O
(1),O
(1′):O
(3)]nickel(II)] |
| title_fullStr | Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
O
(1),O
(1′):O
(3)]nickel(II)] |
| title_full_unstemmed | Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
O
(1),O
(1′):O
(3)]nickel(II)] |
| title_short | Poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
N:N′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
O
(1),O
(1′):O
(3)]nickel(II)] |
| title_sort | poly[aqua[μ-1,2-bis(pyridin-4-yl)ethene-κ(2)
n:n′][μ-5-(diphenylphosphinoyl)isophthalato-κ(3)
o
(1),o
(1′):o
(3)]nickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414124/ https://www.ncbi.nlm.nih.gov/pubmed/22904731 http://dx.doi.org/10.1107/S1600536812031108 |
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