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(2,2′-Bipyridine-κ(2) N,N′)bis(4-formylbenzoato-κO (1))copper(II)
The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formylbenzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414126/ https://www.ncbi.nlm.nih.gov/pubmed/22904733 http://dx.doi.org/10.1107/S1600536812031066 |
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author | Qi, Jin-li Xu, Wei |
author_facet | Qi, Jin-li Xu, Wei |
author_sort | Qi, Jin-li |
collection | PubMed |
description | The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formylbenzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxylate groups of two L (−) ligands, exhibiting effectively a distorted square-planar geometry. The complex molecules are interlinked to generate two-dimensional supramolecular layers in the ab plane, formed by C—H⋯O hydrogen bonds, where the O acceptor is the O atom from the carboxylate group not involved in coordination to the Cu(II) ion. The two-dimensional layers are stacked in a sequence via C—H⋯O hydrogen-bonding interactions where the formyl O atom acts as acceptor. |
format | Online Article Text |
id | pubmed-3414126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141262012-08-17 (2,2′-Bipyridine-κ(2) N,N′)bis(4-formylbenzoato-κO (1))copper(II) Qi, Jin-li Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formylbenzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxylate groups of two L (−) ligands, exhibiting effectively a distorted square-planar geometry. The complex molecules are interlinked to generate two-dimensional supramolecular layers in the ab plane, formed by C—H⋯O hydrogen bonds, where the O acceptor is the O atom from the carboxylate group not involved in coordination to the Cu(II) ion. The two-dimensional layers are stacked in a sequence via C—H⋯O hydrogen-bonding interactions where the formyl O atom acts as acceptor. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414126/ /pubmed/22904733 http://dx.doi.org/10.1107/S1600536812031066 Text en © Qi and Xu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Qi, Jin-li Xu, Wei (2,2′-Bipyridine-κ(2) N,N′)bis(4-formylbenzoato-κO (1))copper(II) |
title | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-formylbenzoato-κO
(1))copper(II) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-formylbenzoato-κO
(1))copper(II) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-formylbenzoato-κO
(1))copper(II) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-formylbenzoato-κO
(1))copper(II) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)bis(4-formylbenzoato-κO
(1))copper(II) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)bis(4-formylbenzoato-κo
(1))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414126/ https://www.ncbi.nlm.nih.gov/pubmed/22904733 http://dx.doi.org/10.1107/S1600536812031066 |
work_keys_str_mv | AT qijinli 22bipyridinek2nnbis4formylbenzoatoko1copperii AT xuwei 22bipyridinek2nnbis4formylbenzoatoko1copperii |