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(2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)

The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formyl­benzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two...

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Detalles Bibliográficos
Autores principales: Qi, Jin-li, Xu, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414126/
https://www.ncbi.nlm.nih.gov/pubmed/22904733
http://dx.doi.org/10.1107/S1600536812031066
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author Qi, Jin-li
Xu, Wei
author_facet Qi, Jin-li
Xu, Wei
author_sort Qi, Jin-li
collection PubMed
description The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formyl­benzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxyl­ate groups of two L (−) ligands, exhibiting effectively a distorted square-planar geometry. The complex mol­ecules are inter­linked to generate two-dimensional supra­molecular layers in the ab plane, formed by C—H⋯O hydrogen bonds, where the O acceptor is the O atom from the carboxyl­ate group not involved in coordination to the Cu(II) ion. The two-dimensional layers are stacked in a sequence via C—H⋯O hydrogen-bonding inter­actions where the formyl O atom acts as acceptor.
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spelling pubmed-34141262012-08-17 (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II) Qi, Jin-li Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formyl­benzoate (L (−)) ligands and a 2,2′-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxyl­ate groups of two L (−) ligands, exhibiting effectively a distorted square-planar geometry. The complex mol­ecules are inter­linked to generate two-dimensional supra­molecular layers in the ab plane, formed by C—H⋯O hydrogen bonds, where the O acceptor is the O atom from the carboxyl­ate group not involved in coordination to the Cu(II) ion. The two-dimensional layers are stacked in a sequence via C—H⋯O hydrogen-bonding inter­actions where the formyl O atom acts as acceptor. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414126/ /pubmed/22904733 http://dx.doi.org/10.1107/S1600536812031066 Text en © Qi and Xu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qi, Jin-li
Xu, Wei
(2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title_full (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title_short (2,2′-Bipyridine-κ(2) N,N′)bis­(4-formyl­benzoato-κO (1))copper(II)
title_sort (2,2′-bipyridine-κ(2) n,n′)bis­(4-formyl­benzoato-κo (1))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414126/
https://www.ncbi.nlm.nih.gov/pubmed/22904733
http://dx.doi.org/10.1107/S1600536812031066
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