(2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate

In the title compound, [Fe(2)(C(5)H(5))(2)(C(18)H(16)O)]·CH(2)Cl(2), the C=C bonds both adopt E conformations. In one ferrocenyl group, the five-membered rings are in a near-eclipsed conformation, whereas in the other they are mutually rotated by ca 21.5°. The central cyclo­hexa­none ring adopts a s...

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Detalles Bibliográficos
Autores principales: Long, Shi-Jia, Yang, Wu, Liu, Yong-Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414127/
https://www.ncbi.nlm.nih.gov/pubmed/22904734
http://dx.doi.org/10.1107/S1600536812030899
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author Long, Shi-Jia
Yang, Wu
Liu, Yong-Hong
author_facet Long, Shi-Jia
Yang, Wu
Liu, Yong-Hong
author_sort Long, Shi-Jia
collection PubMed
description In the title compound, [Fe(2)(C(5)H(5))(2)(C(18)H(16)O)]·CH(2)Cl(2), the C=C bonds both adopt E conformations. In one ferrocenyl group, the five-membered rings are in a near-eclipsed conformation, whereas in the other they are mutually rotated by ca 21.5°. The central cyclo­hexa­none ring adopts a sofa conformation. In the crystal, the dichloro­methane solvent moleucle forms C—H⋯O hydrogen bonds to the organometallic mol­ecules to generate [010] chains of alternating solvent and organometallic species.
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spelling pubmed-34141272012-08-17 (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate Long, Shi-Jia Yang, Wu Liu, Yong-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(5)H(5))(2)(C(18)H(16)O)]·CH(2)Cl(2), the C=C bonds both adopt E conformations. In one ferrocenyl group, the five-membered rings are in a near-eclipsed conformation, whereas in the other they are mutually rotated by ca 21.5°. The central cyclo­hexa­none ring adopts a sofa conformation. In the crystal, the dichloro­methane solvent moleucle forms C—H⋯O hydrogen bonds to the organometallic mol­ecules to generate [010] chains of alternating solvent and organometallic species. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414127/ /pubmed/22904734 http://dx.doi.org/10.1107/S1600536812030899 Text en © Long et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Long, Shi-Jia
Yang, Wu
Liu, Yong-Hong
(2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title_full (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title_fullStr (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title_full_unstemmed (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title_short (2E,6E)-2,6-Bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
title_sort (2e,6e)-2,6-bis(ferrocenyl­methyl­idene)cyclo­hexa­none dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414127/
https://www.ncbi.nlm.nih.gov/pubmed/22904734
http://dx.doi.org/10.1107/S1600536812030899
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AT yangwu 2e6e26bisferrocenylmethylidenecyclohexanonedichloromethanemonosolvate
AT liuyonghong 2e6e26bisferrocenylmethylidenecyclohexanonedichloromethanemonosolvate

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