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Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc

In the title complex, [Zn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate anions, two N,N-diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the...

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Detalles Bibliográficos
Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414129/
https://www.ncbi.nlm.nih.gov/pubmed/22904736
http://dx.doi.org/10.1107/S1600536812031200
Descripción
Sumario:In the title complex, [Zn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate anions, two N,N-diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Zn(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 2.96 (11)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 79.26 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A π–π contact between the parallel pyridine rings of adjacent mol­ecules may further stabilize the crystal structure [centroid–centroid distance = 3.5654 (8) Å].