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Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc

In the title complex, [Zn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate anions, two N,N-diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the...

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Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414129/
https://www.ncbi.nlm.nih.gov/pubmed/22904736
http://dx.doi.org/10.1107/S1600536812031200
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author Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the title complex, [Zn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate anions, two N,N-diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Zn(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 2.96 (11)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 79.26 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A π–π contact between the parallel pyridine rings of adjacent mol­ecules may further stabilize the crystal structure [centroid–centroid distance = 3.5654 (8) Å].
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spelling pubmed-34141292012-08-17 Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate anions, two N,N-diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Zn(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 2.96 (11)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 79.26 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. A π–π contact between the parallel pyridine rings of adjacent mol­ecules may further stabilize the crystal structure [centroid–centroid distance = 3.5654 (8) Å]. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414129/ /pubmed/22904736 http://dx.doi.org/10.1107/S1600536812031200 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title_full Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title_fullStr Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title_full_unstemmed Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title_short Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO (1))zinc
title_sort diaqua­bis­(n,n-diethyl­nicotinamide-κn (1))bis­(4-formyl­benzoato-κo (1))zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414129/
https://www.ncbi.nlm.nih.gov/pubmed/22904736
http://dx.doi.org/10.1107/S1600536812031200
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