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Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II)
Molecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetradentate Schiff base anion in the basal plane and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/ https://www.ncbi.nlm.nih.gov/pubmed/22904737 http://dx.doi.org/10.1107/S1600536812031273 |
Sumario: | Molecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetradentate Schiff base anion in the basal plane and one water molecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intramolecular C—H⋯N and intermolecular C—H⋯O and O—H⋯O hydrogen-bonding interactions, as well as C—H⋯π and π–π stacking interactions [shortest centroid–centroid distance = 3.799 (8) Å and interplanar distance = 3.469 (2) Å] are observed. |
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