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Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)

Mol­ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and...

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Detalles Bibliográficos
Autores principales: Benghanem, Fatiha, Benramdane, Razika, Bouacida, Sofiane, Keraghel, Saida, Ourari, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/
https://www.ncbi.nlm.nih.gov/pubmed/22904737
http://dx.doi.org/10.1107/S1600536812031273
Descripción
Sumario:Mol­ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and one water mol­ecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intra­molecular C—H⋯N and inter­molecular C—H⋯O and O—H⋯O hydrogen-bonding inter­actions, as well as C—H⋯π and π–π stacking inter­actions [shortest centroid–centroid distance = 3.799 (8) Å and inter­planar distance = 3.469 (2) Å] are observed.