Cargando…

Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)

Mol­ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and...

Descripción completa

Detalles Bibliográficos
Autores principales: Benghanem, Fatiha, Benramdane, Razika, Bouacida, Sofiane, Keraghel, Saida, Ourari, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/
https://www.ncbi.nlm.nih.gov/pubmed/22904737
http://dx.doi.org/10.1107/S1600536812031273
_version_ 1782240157764681728
author Benghanem, Fatiha
Benramdane, Razika
Bouacida, Sofiane
Keraghel, Saida
Ourari, Ali
author_facet Benghanem, Fatiha
Benramdane, Razika
Bouacida, Sofiane
Keraghel, Saida
Ourari, Ali
author_sort Benghanem, Fatiha
collection PubMed
description Mol­ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and one water mol­ecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intra­molecular C—H⋯N and inter­molecular C—H⋯O and O—H⋯O hydrogen-bonding inter­actions, as well as C—H⋯π and π–π stacking inter­actions [shortest centroid–centroid distance = 3.799 (8) Å and inter­planar distance = 3.469 (2) Å] are observed.
format Online
Article
Text
id pubmed-3414130
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141302012-08-17 Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II) Benghanem, Fatiha Benramdane, Razika Bouacida, Sofiane Keraghel, Saida Ourari, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Mol­ecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and one water mol­ecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intra­molecular C—H⋯N and inter­molecular C—H⋯O and O—H⋯O hydrogen-bonding inter­actions, as well as C—H⋯π and π–π stacking inter­actions [shortest centroid–centroid distance = 3.799 (8) Å and inter­planar distance = 3.469 (2) Å] are observed. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414130/ /pubmed/22904737 http://dx.doi.org/10.1107/S1600536812031273 Text en © Benghanem et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benghanem, Fatiha
Benramdane, Razika
Bouacida, Sofiane
Keraghel, Saida
Ourari, Ali
Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title_full Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title_fullStr Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title_full_unstemmed Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title_short Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)
title_sort aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/
https://www.ncbi.nlm.nih.gov/pubmed/22904737
http://dx.doi.org/10.1107/S1600536812031273
work_keys_str_mv AT benghanemfatiha aqua44dimethoxy22pyridine23diylbisnitrilomethanylylidenediphenolatocopperii
AT benramdanerazika aqua44dimethoxy22pyridine23diylbisnitrilomethanylylidenediphenolatocopperii
AT bouacidasofiane aqua44dimethoxy22pyridine23diylbisnitrilomethanylylidenediphenolatocopperii
AT keraghelsaida aqua44dimethoxy22pyridine23diylbisnitrilomethanylylidenediphenolatocopperii
AT ourariali aqua44dimethoxy22pyridine23diylbisnitrilomethanylylidenediphenolatocopperii