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Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II)
Molecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetradentate Schiff base anion in the basal plane and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/ https://www.ncbi.nlm.nih.gov/pubmed/22904737 http://dx.doi.org/10.1107/S1600536812031273 |
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author | Benghanem, Fatiha Benramdane, Razika Bouacida, Sofiane Keraghel, Saida Ourari, Ali |
author_facet | Benghanem, Fatiha Benramdane, Razika Bouacida, Sofiane Keraghel, Saida Ourari, Ali |
author_sort | Benghanem, Fatiha |
collection | PubMed |
description | Molecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetradentate Schiff base anion in the basal plane and one water molecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intramolecular C—H⋯N and intermolecular C—H⋯O and O—H⋯O hydrogen-bonding interactions, as well as C—H⋯π and π–π stacking interactions [shortest centroid–centroid distance = 3.799 (8) Å and interplanar distance = 3.469 (2) Å] are observed. |
format | Online Article Text |
id | pubmed-3414130 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141302012-08-17 Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) Benghanem, Fatiha Benramdane, Razika Bouacida, Sofiane Keraghel, Saida Ourari, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Molecules of the title compound, [Cu(C(21)H(17)N(3)O(4))(H(2)O)], lie across a crystallographic mirror plane. The Cu(II) atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetradentate Schiff base anion in the basal plane and one water molecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intramolecular C—H⋯N and intermolecular C—H⋯O and O—H⋯O hydrogen-bonding interactions, as well as C—H⋯π and π–π stacking interactions [shortest centroid–centroid distance = 3.799 (8) Å and interplanar distance = 3.469 (2) Å] are observed. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414130/ /pubmed/22904737 http://dx.doi.org/10.1107/S1600536812031273 Text en © Benghanem et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Benghanem, Fatiha Benramdane, Razika Bouacida, Sofiane Keraghel, Saida Ourari, Ali Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title | Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title_full | Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title_fullStr | Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title_full_unstemmed | Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title_short | Aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) |
title_sort | aqua{4,4′-dimethoxy-2,2′-[pyridine-2,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414130/ https://www.ncbi.nlm.nih.gov/pubmed/22904737 http://dx.doi.org/10.1107/S1600536812031273 |
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