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Poly[[aqua­(μ(2)-4,4′-bipyridine-κ(2) N:N′)[μ(3)-3-bromo-2-(carboxyl­atometh­yl)­benzoato-κ(3) O (1):O (1′):O (2)]cadmium] monohydrate]

In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octa­hedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxyl­ate O atoms...

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Detalles Bibliográficos
Autores principales: Liu, Yangmei, Cao, Kai, Wang, Fenglin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414131/
https://www.ncbi.nlm.nih.gov/pubmed/22904738
http://dx.doi.org/10.1107/S1600536812031297
Descripción
Sumario:In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octa­hedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxyl­ate O atoms from three 3-bromo-2-(carboxyl­atometh­yl)benzoate (bcb) ligands and one O atom from a water mol­ecule. The bipy and bcb ligands link the Cd(II) atoms into a three-dimensional network. O—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and benzene rings [centroid–centroid distance = 3.736 (4) Å] are present in the crystal.