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Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2) N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3) O (1):O (1′):O (2)]cadmium] monohydrate]
In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octahedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxylate O atoms...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414131/ https://www.ncbi.nlm.nih.gov/pubmed/22904738 http://dx.doi.org/10.1107/S1600536812031297 |
| _version_ | 1782240157993271296 |
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| author | Liu, Yangmei Cao, Kai Wang, Fenglin |
| author_facet | Liu, Yangmei Cao, Kai Wang, Fenglin |
| author_sort | Liu, Yangmei |
| collection | PubMed |
| description | In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octahedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxylate O atoms from three 3-bromo-2-(carboxylatomethyl)benzoate (bcb) ligands and one O atom from a water molecule. The bipy and bcb ligands link the Cd(II) atoms into a three-dimensional network. O—H⋯O hydrogen bonds and π–π interactions between the pyridine and benzene rings [centroid–centroid distance = 3.736 (4) Å] are present in the crystal. |
| format | Online Article Text |
| id | pubmed-3414131 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141312012-08-17 Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2) N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3) O (1):O (1′):O (2)]cadmium] monohydrate] Liu, Yangmei Cao, Kai Wang, Fenglin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octahedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxylate O atoms from three 3-bromo-2-(carboxylatomethyl)benzoate (bcb) ligands and one O atom from a water molecule. The bipy and bcb ligands link the Cd(II) atoms into a three-dimensional network. O—H⋯O hydrogen bonds and π–π interactions between the pyridine and benzene rings [centroid–centroid distance = 3.736 (4) Å] are present in the crystal. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414131/ /pubmed/22904738 http://dx.doi.org/10.1107/S1600536812031297 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Yangmei Cao, Kai Wang, Fenglin Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2) N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3) O (1):O (1′):O (2)]cadmium] monohydrate] |
| title | Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
O
(1):O
(1′):O
(2)]cadmium] monohydrate] |
| title_full | Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
O
(1):O
(1′):O
(2)]cadmium] monohydrate] |
| title_fullStr | Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
O
(1):O
(1′):O
(2)]cadmium] monohydrate] |
| title_full_unstemmed | Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
O
(1):O
(1′):O
(2)]cadmium] monohydrate] |
| title_short | Poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
N:N′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
O
(1):O
(1′):O
(2)]cadmium] monohydrate] |
| title_sort | poly[[aqua(μ(2)-4,4′-bipyridine-κ(2)
n:n′)[μ(3)-3-bromo-2-(carboxylatomethyl)benzoato-κ(3)
o
(1):o
(1′):o
(2)]cadmium] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414131/ https://www.ncbi.nlm.nih.gov/pubmed/22904738 http://dx.doi.org/10.1107/S1600536812031297 |
| work_keys_str_mv | AT liuyangmei polyaquam244bipyridinek2nnm33bromo2carboxylatomethylbenzoatok3o1o1o2cadmiummonohydrate AT caokai polyaquam244bipyridinek2nnm33bromo2carboxylatomethylbenzoatok3o1o1o2cadmiummonohydrate AT wangfenglin polyaquam244bipyridinek2nnm33bromo2carboxylatomethylbenzoatok3o1o1o2cadmiummonohydrate |