Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate

In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis­(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral environment. In the crystal, the picrate anions and methanol solvent mol­...

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Detalles Bibliográficos
Autores principales: Fan, Xuyang, Yuan, Jingkun, Bai, Ying, Kong, Jin, Wu, Huilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414132/
https://www.ncbi.nlm.nih.gov/pubmed/22904739
http://dx.doi.org/10.1107/S1600536812031443
Descripción
Sumario:In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis­(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral environment. In the crystal, the picrate anions and methanol solvent mol­ecules are connected by O—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O hydrogen bonds are also observed.

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