Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate

In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis­(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral environment. In the crystal, the picrate anions and methanol solvent mol­...

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Detalles Bibliográficos
Autores principales: Fan, Xuyang, Yuan, Jingkun, Bai, Ying, Kong, Jin, Wu, Huilu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414132/
https://www.ncbi.nlm.nih.gov/pubmed/22904739
http://dx.doi.org/10.1107/S1600536812031443
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author Fan, Xuyang
Yuan, Jingkun
Bai, Ying
Kong, Jin
Wu, Huilu
author_facet Fan, Xuyang
Yuan, Jingkun
Bai, Ying
Kong, Jin
Wu, Huilu
author_sort Fan, Xuyang
collection PubMed
description In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis­(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral environment. In the crystal, the picrate anions and methanol solvent mol­ecules are connected by O—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O hydrogen bonds are also observed.
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spelling pubmed-34141322012-08-17 Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate Fan, Xuyang Yuan, Jingkun Bai, Ying Kong, Jin Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis­(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa­hedral environment. In the crystal, the picrate anions and methanol solvent mol­ecules are connected by O—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414132/ /pubmed/22904739 http://dx.doi.org/10.1107/S1600536812031443 Text en © Fan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Xuyang
Yuan, Jingkun
Bai, Ying
Kong, Jin
Wu, Huilu
Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title_full Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title_fullStr Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title_full_unstemmed Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title_short Bis[2,6-bis­(1-methyl-1H-benzimidazol-2-yl-κN (3))pyridine-κN]zinc dipicrate methanol disolvate
title_sort bis[2,6-bis­(1-methyl-1h-benzimidazol-2-yl-κn (3))pyridine-κn]zinc dipicrate methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414132/
https://www.ncbi.nlm.nih.gov/pubmed/22904739
http://dx.doi.org/10.1107/S1600536812031443
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