trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)

In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter­ac...

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Detalles Bibliográficos
Autores principales: Warsink, Stefan, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414134/
https://www.ncbi.nlm.nih.gov/pubmed/22904741
http://dx.doi.org/10.1107/S1600536812031868
Descripción
Sumario:In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter­actions, the most significant of which is a hydrogen bond between the amide moiety of the NHC and the chloride ligand. These hydrogen-bond interactions form a three-dimensional network.

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