trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)

In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter­ac...

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Detalles Bibliográficos
Autores principales: Warsink, Stefan, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414134/
https://www.ncbi.nlm.nih.gov/pubmed/22904741
http://dx.doi.org/10.1107/S1600536812031868
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author Warsink, Stefan
Roodt, Andreas
author_facet Warsink, Stefan
Roodt, Andreas
author_sort Warsink, Stefan
collection PubMed
description In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter­actions, the most significant of which is a hydrogen bond between the amide moiety of the NHC and the chloride ligand. These hydrogen-bond interactions form a three-dimensional network.
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spelling pubmed-34141342012-08-17 trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II) Warsink, Stefan Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(21)H(23)N(3)O)(2)], the Pd(II) atom is located on an inversion centre and is coordinated in a slightly distorted square-planar environment by the chloride and N-heterocyclic carbene (NHC) ligands in mutual trans positions. There are several hydrogen-bonding inter­actions, the most significant of which is a hydrogen bond between the amide moiety of the NHC and the chloride ligand. These hydrogen-bond interactions form a three-dimensional network. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414134/ /pubmed/22904741 http://dx.doi.org/10.1107/S1600536812031868 Text en © Warsink and Roodt 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warsink, Stefan
Roodt, Andreas
trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title_full trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title_fullStr trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title_full_unstemmed trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title_short trans-Bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(II)
title_sort trans-bis[1-(2-benzamido­eth­yl)-3-(2,4,6-trimethyl­phen­yl)imidazol-2-yl­idene]dichloridopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414134/
https://www.ncbi.nlm.nih.gov/pubmed/22904741
http://dx.doi.org/10.1107/S1600536812031868
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