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catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato]
In the title compound, [Co(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Co(II) atom is six-coordinated in a distorted octahedral coordination geometry by four O atoms from two chelating carboxylate groups from different 2,4′-oxydibenzoate anions and by two N atoms from a 1,10-phenanthroline (phen) ligan...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414136/ https://www.ncbi.nlm.nih.gov/pubmed/22904743 http://dx.doi.org/10.1107/S1600536812031534 |
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author | Guo, Hai-Kang Fu, Feng Tang, Long Hou, Xiang-Yang Cao, Jia |
author_facet | Guo, Hai-Kang Fu, Feng Tang, Long Hou, Xiang-Yang Cao, Jia |
author_sort | Guo, Hai-Kang |
collection | PubMed |
description | In the title compound, [Co(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Co(II) atom is six-coordinated in a distorted octahedral coordination geometry by four O atoms from two chelating carboxylate groups from different 2,4′-oxydibenzoate anions and by two N atoms from a 1,10-phenanthroline (phen) ligand. The two benzene rings of the 2,4′-oxydibenzoate ligand form a dihedral angle of 77.14 (16)°. Adjacent Co(II) atoms are bridged by 2,4′-oxydibenzoate anions to form a helical chain that propagates along the b-axis direction. Neighboring chains are further assembled by intermolecular π–π stacking interactions between inversion-related phen ligands [centroid-to-centroid distance = 4.0869 (8) Å] to form a two-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3414136 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141362012-08-17 catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] Guo, Hai-Kang Fu, Feng Tang, Long Hou, Xiang-Yang Cao, Jia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Co(II) atom is six-coordinated in a distorted octahedral coordination geometry by four O atoms from two chelating carboxylate groups from different 2,4′-oxydibenzoate anions and by two N atoms from a 1,10-phenanthroline (phen) ligand. The two benzene rings of the 2,4′-oxydibenzoate ligand form a dihedral angle of 77.14 (16)°. Adjacent Co(II) atoms are bridged by 2,4′-oxydibenzoate anions to form a helical chain that propagates along the b-axis direction. Neighboring chains are further assembled by intermolecular π–π stacking interactions between inversion-related phen ligands [centroid-to-centroid distance = 4.0869 (8) Å] to form a two-dimensional supramolecular architecture. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414136/ /pubmed/22904743 http://dx.doi.org/10.1107/S1600536812031534 Text en © Guo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Hai-Kang Fu, Feng Tang, Long Hou, Xiang-Yang Cao, Jia catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title |
catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title_full |
catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title_short |
catena-Poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
title_sort | catena-poly[[(1,10-phenanthroline)cobalt]-μ-2,4′-oxydibenzoato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414136/ https://www.ncbi.nlm.nih.gov/pubmed/22904743 http://dx.doi.org/10.1107/S1600536812031534 |
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