(Acetyl­acetonato-κ(2) O,O′)bis­{5-fluoro-2-[3-(4-fluoro­phen­yl)pyrazin-2-yl]phenyl-κ(2) N (1),C (1)}iridium(III)

In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa­coordinated in a distorted octa­hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro­phen­yl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetyl­acetonate ligand....

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Detalles Bibliográficos
Autores principales: Ge, Guo-Ping, Li, Chun-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414137/
https://www.ncbi.nlm.nih.gov/pubmed/22904744
http://dx.doi.org/10.1107/S1600536812031546
Descripción
Sumario:In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexa­coordinated in a distorted octa­hedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluoro­phen­yl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetyl­acetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°.

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