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(Acetylacetonato-κ(2) O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2) N (1),C (1)}iridium(III)
In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetylacetonate ligand....
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414137/ https://www.ncbi.nlm.nih.gov/pubmed/22904744 http://dx.doi.org/10.1107/S1600536812031546 |
| _version_ | 1782240159326011392 |
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| author | Ge, Guo-Ping Li, Chun-Yan |
| author_facet | Ge, Guo-Ping Li, Chun-Yan |
| author_sort | Ge, Guo-Ping |
| collection | PubMed |
| description | In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetylacetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°. |
| format | Online Article Text |
| id | pubmed-3414137 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141372012-08-17 (Acetylacetonato-κ(2) O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2) N (1),C (1)}iridium(III) Ge, Guo-Ping Li, Chun-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(16)H(9)F(2)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom, lying on a twofold rotation axis, is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetylacetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414137/ /pubmed/22904744 http://dx.doi.org/10.1107/S1600536812031546 Text en © Ge and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ge, Guo-Ping Li, Chun-Yan (Acetylacetonato-κ(2) O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2) N (1),C (1)}iridium(III) |
| title | (Acetylacetonato-κ(2)
O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
N
(1),C
(1)}iridium(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
N
(1),C
(1)}iridium(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
N
(1),C
(1)}iridium(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
N
(1),C
(1)}iridium(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
N
(1),C
(1)}iridium(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ(2)
n
(1),c
(1)}iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414137/ https://www.ncbi.nlm.nih.gov/pubmed/22904744 http://dx.doi.org/10.1107/S1600536812031546 |
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