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Bis(acetato-κO)bis­(2-pyridine­aldoxime-κ(2) N,N′)cadmium

In the title mol­ecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N′-chelated by two 2-pyridine­aldoxime ligands and coordinated by two acetate anions in a distorted octa­hedral geometry. The hy­droxy groups of the 2-pyridine­aldoxime ligands link to the acetate anions via intra­mo...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414138/
https://www.ncbi.nlm.nih.gov/pubmed/22904745
http://dx.doi.org/10.1107/S1600536812031819
Descripción
Sumario:In the title mol­ecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N′-chelated by two 2-pyridine­aldoxime ligands and coordinated by two acetate anions in a distorted octa­hedral geometry. The hy­droxy groups of the 2-pyridine­aldoxime ligands link to the acetate anions via intra­molecular O—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯O hydrogen bonds occur in the crystal.