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Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2) N,N′)cadmium
In the title molecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N′-chelated by two 2-pyridinealdoxime ligands and coordinated by two acetate anions in a distorted octahedral geometry. The hydroxy groups of the 2-pyridinealdoxime ligands link to the acetate anions via intramo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414138/ https://www.ncbi.nlm.nih.gov/pubmed/22904745 http://dx.doi.org/10.1107/S1600536812031819 |
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author | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_facet | Shirvan, Sadif A. Haydari Dezfuli, Sara |
author_sort | Shirvan, Sadif A. |
collection | PubMed |
description | In the title molecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N′-chelated by two 2-pyridinealdoxime ligands and coordinated by two acetate anions in a distorted octahedral geometry. The hydroxy groups of the 2-pyridinealdoxime ligands link to the acetate anions via intramolecular O—H⋯O hydrogen bonds. Weak intermolecular C—H⋯O hydrogen bonds occur in the crystal. |
format | Online Article Text |
id | pubmed-3414138 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141382012-08-17 Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2) N,N′)cadmium Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N′-chelated by two 2-pyridinealdoxime ligands and coordinated by two acetate anions in a distorted octahedral geometry. The hydroxy groups of the 2-pyridinealdoxime ligands link to the acetate anions via intramolecular O—H⋯O hydrogen bonds. Weak intermolecular C—H⋯O hydrogen bonds occur in the crystal. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414138/ /pubmed/22904745 http://dx.doi.org/10.1107/S1600536812031819 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shirvan, Sadif A. Haydari Dezfuli, Sara Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2) N,N′)cadmium |
title | Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2)
N,N′)cadmium |
title_full | Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2)
N,N′)cadmium |
title_fullStr | Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2)
N,N′)cadmium |
title_full_unstemmed | Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2)
N,N′)cadmium |
title_short | Bis(acetato-κO)bis(2-pyridinealdoxime-κ(2)
N,N′)cadmium |
title_sort | bis(acetato-κo)bis(2-pyridinealdoxime-κ(2)
n,n′)cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414138/ https://www.ncbi.nlm.nih.gov/pubmed/22904745 http://dx.doi.org/10.1107/S1600536812031819 |
work_keys_str_mv | AT shirvansadifa bisacetatokobis2pyridinealdoximek2nncadmium AT haydaridezfulisara bisacetatokobis2pyridinealdoximek2nncadmium |