Di-μ-acetato-κ(4) O:O-bis­({N′-[(E)-phen­yl­(pyridin-2-yl-κN)methyl­idene]benzo­hydrazidato-κ(2) N′,O}copper(II))

The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-p...

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Detalles Bibliográficos
Autores principales: Vineetha, M. C., Sithambaresan, M., Jacob, Jinsa Mary, Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414141/
https://www.ncbi.nlm.nih.gov/pubmed/22904748
http://dx.doi.org/10.1107/S1600536812031467
Descripción
Sumario:The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-pyramidal coordination geometry. The crystal packing involves inter­molecular C—H⋯O, C—H⋯N and C—H⋯π and two types of π–π inter­actions, with centroid–centroid distances of 3.9958 (10) and 3.7016 (13) Å.

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