Cargando…
Di-μ-acetato-κ(4) O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2) N′,O}copper(II))
The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-p...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414141/ https://www.ncbi.nlm.nih.gov/pubmed/22904748 http://dx.doi.org/10.1107/S1600536812031467 |
| _version_ | 1782240160226738176 |
|---|---|
| author | Vineetha, M. C. Sithambaresan, M. Jacob, Jinsa Mary Kurup, M. R. Prathapachandra |
| author_facet | Vineetha, M. C. Sithambaresan, M. Jacob, Jinsa Mary Kurup, M. R. Prathapachandra |
| author_sort | Vineetha, M. C. |
| collection | PubMed |
| description | The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-pyramidal coordination geometry. The crystal packing involves intermolecular C—H⋯O, C—H⋯N and C—H⋯π and two types of π–π interactions, with centroid–centroid distances of 3.9958 (10) and 3.7016 (13) Å. |
| format | Online Article Text |
| id | pubmed-3414141 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141412012-08-17 Di-μ-acetato-κ(4) O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2) N′,O}copper(II)) Vineetha, M. C. Sithambaresan, M. Jacob, Jinsa Mary Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-pyramidal coordination geometry. The crystal packing involves intermolecular C—H⋯O, C—H⋯N and C—H⋯π and two types of π–π interactions, with centroid–centroid distances of 3.9958 (10) and 3.7016 (13) Å. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414141/ /pubmed/22904748 http://dx.doi.org/10.1107/S1600536812031467 Text en © Vineetha et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vineetha, M. C. Sithambaresan, M. Jacob, Jinsa Mary Kurup, M. R. Prathapachandra Di-μ-acetato-κ(4) O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2) N′,O}copper(II)) |
| title | Di-μ-acetato-κ(4)
O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2)
N′,O}copper(II)) |
| title_full | Di-μ-acetato-κ(4)
O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2)
N′,O}copper(II)) |
| title_fullStr | Di-μ-acetato-κ(4)
O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2)
N′,O}copper(II)) |
| title_full_unstemmed | Di-μ-acetato-κ(4)
O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2)
N′,O}copper(II)) |
| title_short | Di-μ-acetato-κ(4)
O:O-bis({N′-[(E)-phenyl(pyridin-2-yl-κN)methylidene]benzohydrazidato-κ(2)
N′,O}copper(II)) |
| title_sort | di-μ-acetato-κ(4)
o:o-bis({n′-[(e)-phenyl(pyridin-2-yl-κn)methylidene]benzohydrazidato-κ(2)
n′,o}copper(ii)) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414141/ https://www.ncbi.nlm.nih.gov/pubmed/22904748 http://dx.doi.org/10.1107/S1600536812031467 |
| work_keys_str_mv | AT vineethamc dimacetatok4oobisnephenylpyridin2ylknmethylidenebenzohydrazidatok2nocopperii AT sithambaresanm dimacetatok4oobisnephenylpyridin2ylknmethylidenebenzohydrazidatok2nocopperii AT jacobjinsamary dimacetatok4oobisnephenylpyridin2ylknmethylidenebenzohydrazidatok2nocopperii AT kurupmrprathapachandra dimacetatok4oobisnephenylpyridin2ylknmethylidenebenzohydrazidatok2nocopperii |