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Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2) N:O (1))diaquazinc] dihydrate]
The Zn(II) atom in the title polymeric compound, {[Zn(C(8)H(6)NO(4))(2)(H(2)O)(2)]·2H(2)O}(n), lies on a center of inversion and is coordinated by two amine N atoms and two carboxylate O atoms from two 3-amino-5-carboxybenzoate anions along with two water molecules in a distorted octahedral geo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414142/ https://www.ncbi.nlm.nih.gov/pubmed/22904749 http://dx.doi.org/10.1107/S1600536812031789 |
| _version_ | 1782240160453230592 |
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| author | Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng |
| author_facet | Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng |
| author_sort | Zhang, Kou-Lin |
| collection | PubMed |
| description | The Zn(II) atom in the title polymeric compound, {[Zn(C(8)H(6)NO(4))(2)(H(2)O)(2)]·2H(2)O}(n), lies on a center of inversion and is coordinated by two amine N atoms and two carboxylate O atoms from two 3-amino-5-carboxybenzoate anions along with two water molecules in a distorted octahedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N—H⋯O and O—H⋯O types exist in the structure. One H atom of the coordinated water molecule and one H atom of the solvent water molecule are each disordered over two positions in a 1:1 ratio. |
| format | Online Article Text |
| id | pubmed-3414142 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141422012-08-17 Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2) N:O (1))diaquazinc] dihydrate] Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title polymeric compound, {[Zn(C(8)H(6)NO(4))(2)(H(2)O)(2)]·2H(2)O}(n), lies on a center of inversion and is coordinated by two amine N atoms and two carboxylate O atoms from two 3-amino-5-carboxybenzoate anions along with two water molecules in a distorted octahedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N—H⋯O and O—H⋯O types exist in the structure. One H atom of the coordinated water molecule and one H atom of the solvent water molecule are each disordered over two positions in a 1:1 ratio. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414142/ /pubmed/22904749 http://dx.doi.org/10.1107/S1600536812031789 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2) N:O (1))diaquazinc] dihydrate] |
| title | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
N:O
(1))diaquazinc] dihydrate] |
| title_full | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
N:O
(1))diaquazinc] dihydrate] |
| title_fullStr | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
N:O
(1))diaquazinc] dihydrate] |
| title_full_unstemmed | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
N:O
(1))diaquazinc] dihydrate] |
| title_short | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
N:O
(1))diaquazinc] dihydrate] |
| title_sort | poly[[bis(μ-3-amino-5-carboxybenzoato-κ(2)
n:o
(1))diaquazinc] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414142/ https://www.ncbi.nlm.nih.gov/pubmed/22904749 http://dx.doi.org/10.1107/S1600536812031789 |
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