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(Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate

The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent mol­ecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the...

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Autores principales: Jacob, Jinsa Mary, Prathapachandra Kurup, M. R., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414143/
https://www.ncbi.nlm.nih.gov/pubmed/22904750
http://dx.doi.org/10.1107/S1600536812031777
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author Jacob, Jinsa Mary
Prathapachandra Kurup, M. R.
Ng, Seik Weng
author_facet Jacob, Jinsa Mary
Prathapachandra Kurup, M. R.
Ng, Seik Weng
author_sort Jacob, Jinsa Mary
collection PubMed
description The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent mol­ecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethyl­formamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin.
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spelling pubmed-34141432012-08-17 (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent mol­ecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethyl­formamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414143/ /pubmed/22904750 http://dx.doi.org/10.1107/S1600536812031777 Text en © Jacob et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jacob, Jinsa Mary
Prathapachandra Kurup, M. R.
Ng, Seik Weng
(Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title_full (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title_fullStr (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title_full_unstemmed (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title_short (Anilino{(Z)-2-[(E)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) O (2),N (2)}methane­thiol­ato-κS)(4,4′-di­methyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethyl­formamide monosolvate
title_sort (anilino{(z)-2-[(e)-5-bromo-3-meth­oxy-2-oxidobenzyl­idene]hydrazin-1-yl­idene-κ(2) o (2),n (2)}methane­thiol­ato-κs)(4,4′-di­methyl-2,2′-bipyridine-κ(2) n,n′)zinc n,n-dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414143/
https://www.ncbi.nlm.nih.gov/pubmed/22904750
http://dx.doi.org/10.1107/S1600536812031777
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