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(Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2) O (2),N (2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethylformamide monosolvate
The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent molecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414143/ https://www.ncbi.nlm.nih.gov/pubmed/22904750 http://dx.doi.org/10.1107/S1600536812031777 |
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author | Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng |
author_facet | Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng |
author_sort | Jacob, Jinsa Mary |
collection | PubMed |
description | The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent molecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethylformamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin. |
format | Online Article Text |
id | pubmed-3414143 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141432012-08-17 (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2) O (2),N (2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethylformamide monosolvate Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent molecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethylformamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414143/ /pubmed/22904750 http://dx.doi.org/10.1107/S1600536812031777 Text en © Jacob et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jacob, Jinsa Mary Prathapachandra Kurup, M. R. Ng, Seik Weng (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2) O (2),N (2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc N,N-dimethylformamide monosolvate |
title | (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
O
(2),N
(2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc N,N-dimethylformamide monosolvate |
title_full | (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
O
(2),N
(2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc N,N-dimethylformamide monosolvate |
title_fullStr | (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
O
(2),N
(2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc N,N-dimethylformamide monosolvate |
title_full_unstemmed | (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
O
(2),N
(2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc N,N-dimethylformamide monosolvate |
title_short | (Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
O
(2),N
(2)}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc N,N-dimethylformamide monosolvate |
title_sort | (anilino{(z)-2-[(e)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ(2)
o
(2),n
(2)}methanethiolato-κs)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc n,n-dimethylformamide monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414143/ https://www.ncbi.nlm.nih.gov/pubmed/22904750 http://dx.doi.org/10.1107/S1600536812031777 |
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