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{4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)
The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of t...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414144/ https://www.ncbi.nlm.nih.gov/pubmed/22904751 http://dx.doi.org/10.1107/S1600536812032138 |
| _version_ | 1782240160893632512 |
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| author | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
| author_facet | Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz |
| author_sort | Kargar, Hadi |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant intermolecular interactions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944 (1):0.056 (1). |
| format | Online Article Text |
| id | pubmed-3414144 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141442012-08-17 {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant intermolecular interactions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944 (1):0.056 (1). International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414144/ /pubmed/22904751 http://dx.doi.org/10.1107/S1600536812032138 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Adabi Ardakani, Amir Tahir, Muhammad Nawaz {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) |
| title | {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full | {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_fullStr | {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full_unstemmed | {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_short | {4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_sort | {4,4′,6,6′-tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
o,n,n′,o′}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414144/ https://www.ncbi.nlm.nih.gov/pubmed/22904751 http://dx.doi.org/10.1107/S1600536812032138 |
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