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Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II)
In the title complex, [Co(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) cat...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414145/ https://www.ncbi.nlm.nih.gov/pubmed/22904752 http://dx.doi.org/10.1107/S1600536812032205 |
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author | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Sertçelik, Mustafa |
collection | PubMed |
description | In the title complex, [Co(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.91 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 88.84 (4)°. The coordinating water molecule links with the carboxylate group via an intramolecular O—H⋯O hydrogen bond. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. π–π stacking between the parallel benzene rings of adjacent molecules [centroid–centroid distance = 3.8505 (8) Å] may further stabilize the structure. A weak C—H⋯π interaction also occurs in the crystal. |
format | Online Article Text |
id | pubmed-3414145 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141452012-08-17 Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II) Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coordinated by two 4-formylbenzoate (FB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 23.91 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 88.84 (4)°. The coordinating water molecule links with the carboxylate group via an intramolecular O—H⋯O hydrogen bond. In the crystal, N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular network. π–π stacking between the parallel benzene rings of adjacent molecules [centroid–centroid distance = 3.8505 (8) Å] may further stabilize the structure. A weak C—H⋯π interaction also occurs in the crystal. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414145/ /pubmed/22904752 http://dx.doi.org/10.1107/S1600536812032205 Text en © Sertçelik et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Diaquabis(4-formylbenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II) |
title | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) |
title_full | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) |
title_fullStr | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) |
title_full_unstemmed | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) |
title_short | Diaquabis(4-formylbenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) |
title_sort | diaquabis(4-formylbenzoato-κo
(1))bis(nicotinamide-κn
(1))cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414145/ https://www.ncbi.nlm.nih.gov/pubmed/22904752 http://dx.doi.org/10.1107/S1600536812032205 |
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