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Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)

In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two seleno­cyanate anions, two 2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine ligands and two water mol­ecules within a slightly distorted N(4)O(2) octa­hedron. The asymmetric unit consists of one Co(2+) ca...

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Detalles Bibliográficos
Autores principales: Liu, Yuan-Yuan, Yang, Pan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414148/
https://www.ncbi.nlm.nih.gov/pubmed/22904755
http://dx.doi.org/10.1107/S1600536812032461
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author Liu, Yuan-Yuan
Yang, Pan
author_facet Liu, Yuan-Yuan
Yang, Pan
author_sort Liu, Yuan-Yuan
collection PubMed
description In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two seleno­cyanate anions, two 2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine ligands and two water mol­ecules within a slightly distorted N(4)O(2) octa­hedron. The asymmetric unit consists of one Co(2+) cation, which is located on a center of inversion, as well as one seleno­cyanate anion, one 2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine ligand and one water mol­ecule in general positions. Inter­molecular O—H⋯N hydrogen bonds join the complex mol­ecules into layers parallel to the bc plane. The layers are linked by C—H⋯N and C—H⋯Se hydrogen bonds into a three-dimensional supra­molecular architecture.
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spelling pubmed-34141482012-08-17 Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II) Liu, Yuan-Yuan Yang, Pan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two seleno­cyanate anions, two 2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine ligands and two water mol­ecules within a slightly distorted N(4)O(2) octa­hedron. The asymmetric unit consists of one Co(2+) cation, which is located on a center of inversion, as well as one seleno­cyanate anion, one 2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine ligand and one water mol­ecule in general positions. Inter­molecular O—H⋯N hydrogen bonds join the complex mol­ecules into layers parallel to the bc plane. The layers are linked by C—H⋯N and C—H⋯Se hydrogen bonds into a three-dimensional supra­molecular architecture. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414148/ /pubmed/22904755 http://dx.doi.org/10.1107/S1600536812032461 Text en © Liu and Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yuan-Yuan
Yang, Pan
Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title_full Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title_fullStr Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title_full_unstemmed Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title_short Diaqua­bis­[2,6-bis­(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis­(seleno­cyanato-κN)cobalt(II)
title_sort diaqua­bis­[2,6-bis­(4h-1,2,4-triazol-4-yl)pyridine-κn (2)]bis­(seleno­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414148/
https://www.ncbi.nlm.nih.gov/pubmed/22904755
http://dx.doi.org/10.1107/S1600536812032461
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