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Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis(selenocyanato-κN)cobalt(II)
In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two selenocyanate anions, two 2,6-bis(4H-1,2,4-triazol-4-yl)pyridine ligands and two water molecules within a slightly distorted N(4)O(2) octahedron. The asymmetric unit consists of one Co(2+) ca...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414148/ https://www.ncbi.nlm.nih.gov/pubmed/22904755 http://dx.doi.org/10.1107/S1600536812032461 |
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author | Liu, Yuan-Yuan Yang, Pan |
author_facet | Liu, Yuan-Yuan Yang, Pan |
author_sort | Liu, Yuan-Yuan |
collection | PubMed |
description | In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two selenocyanate anions, two 2,6-bis(4H-1,2,4-triazol-4-yl)pyridine ligands and two water molecules within a slightly distorted N(4)O(2) octahedron. The asymmetric unit consists of one Co(2+) cation, which is located on a center of inversion, as well as one selenocyanate anion, one 2,6-bis(4H-1,2,4-triazol-4-yl)pyridine ligand and one water molecule in general positions. Intermolecular O—H⋯N hydrogen bonds join the complex molecules into layers parallel to the bc plane. The layers are linked by C—H⋯N and C—H⋯Se hydrogen bonds into a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3414148 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141482012-08-17 Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis(selenocyanato-κN)cobalt(II) Liu, Yuan-Yuan Yang, Pan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCSe)(2)(C(9)H(7)N(7))(2)(H(2)O)(2)], the Co(2+) cation is coordinated by two selenocyanate anions, two 2,6-bis(4H-1,2,4-triazol-4-yl)pyridine ligands and two water molecules within a slightly distorted N(4)O(2) octahedron. The asymmetric unit consists of one Co(2+) cation, which is located on a center of inversion, as well as one selenocyanate anion, one 2,6-bis(4H-1,2,4-triazol-4-yl)pyridine ligand and one water molecule in general positions. Intermolecular O—H⋯N hydrogen bonds join the complex molecules into layers parallel to the bc plane. The layers are linked by C—H⋯N and C—H⋯Se hydrogen bonds into a three-dimensional supramolecular architecture. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414148/ /pubmed/22904755 http://dx.doi.org/10.1107/S1600536812032461 Text en © Liu and Yang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yuan-Yuan Yang, Pan Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN (2)]bis(selenocyanato-κN)cobalt(II) |
title | Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN
(2)]bis(selenocyanato-κN)cobalt(II) |
title_full | Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN
(2)]bis(selenocyanato-κN)cobalt(II) |
title_fullStr | Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN
(2)]bis(selenocyanato-κN)cobalt(II) |
title_full_unstemmed | Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN
(2)]bis(selenocyanato-κN)cobalt(II) |
title_short | Diaquabis[2,6-bis(4H-1,2,4-triazol-4-yl)pyridine-κN
(2)]bis(selenocyanato-κN)cobalt(II) |
title_sort | diaquabis[2,6-bis(4h-1,2,4-triazol-4-yl)pyridine-κn
(2)]bis(selenocyanato-κn)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414148/ https://www.ncbi.nlm.nih.gov/pubmed/22904755 http://dx.doi.org/10.1107/S1600536812032461 |
work_keys_str_mv | AT liuyuanyuan diaquabis26bis4h124triazol4ylpyridinekn2bisselenocyanatokncobaltii AT yangpan diaquabis26bis4h124triazol4ylpyridinekn2bisselenocyanatokncobaltii |