Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)

In the title compound, [HgCl(2)(C(6)H(8)N(2))(2)], the two independent Hg(II) cations are each located on a twofold rotation axis and coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands and two Cl(−) anions in a distorted tetra­hedral geometry. An intra­molecular N—H⋯Cl hy...

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Detalles Bibliográficos
Autores principales: Tadjarodi, Azadeh, Bijanzad, Keyvan, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414149/
https://www.ncbi.nlm.nih.gov/pubmed/22904756
http://dx.doi.org/10.1107/S1600536812032126
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author Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_facet Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_sort Tadjarodi, Azadeh
collection PubMed
description In the title compound, [HgCl(2)(C(6)H(8)N(2))(2)], the two independent Hg(II) cations are each located on a twofold rotation axis and coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands and two Cl(−) anions in a distorted tetra­hedral geometry. An intra­molecular N—H⋯Cl hydrogen bond occurs in each independent complex mol­ecule. Inter­molecular N—H⋯Cl hydrogen bonds occur in the crystal structure.
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spelling pubmed-34141492012-08-17 Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II) Tadjarodi, Azadeh Bijanzad, Keyvan Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(6)H(8)N(2))(2)], the two independent Hg(II) cations are each located on a twofold rotation axis and coordinated by two pyridine N atoms from two 2-amino-3-methyl­pyridine ligands and two Cl(−) anions in a distorted tetra­hedral geometry. An intra­molecular N—H⋯Cl hydrogen bond occurs in each independent complex mol­ecule. Inter­molecular N—H⋯Cl hydrogen bonds occur in the crystal structure. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414149/ /pubmed/22904756 http://dx.doi.org/10.1107/S1600536812032126 Text en © Tadjarodi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title_full Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title_fullStr Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title_full_unstemmed Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title_short Bis(2-amino-3-methyl­pyridine-κN (1))dichloridomercury(II)
title_sort bis(2-amino-3-methyl­pyridine-κn (1))dichloridomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414149/
https://www.ncbi.nlm.nih.gov/pubmed/22904756
http://dx.doi.org/10.1107/S1600536812032126
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