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(Cinnamato-κ(2) O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
In the title compound, [Ni(C(9)H(7)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the Ni(II) atom, which is also chelated by the carboxylate group. The geometry is a distorted N(4)O(2) octahedron. In the...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414150/ https://www.ncbi.nlm.nih.gov/pubmed/22904757 http://dx.doi.org/10.1107/S1600536812032175 |
| _version_ | 1782240162259927040 |
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| author | Gao, Qiang Cao, Yi-Cheng |
| author_facet | Gao, Qiang Cao, Yi-Cheng |
| author_sort | Gao, Qiang |
| collection | PubMed |
| description | In the title compound, [Ni(C(9)H(7)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the Ni(II) atom, which is also chelated by the carboxylate group. The geometry is a distorted N(4)O(2) octahedron. In the crystal, adjacent molecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into a zigzag chain parallel to [010]. |
| format | Online Article Text |
| id | pubmed-3414150 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141502012-08-17 (Cinnamato-κ(2) O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate Gao, Qiang Cao, Yi-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(7)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the Ni(II) atom, which is also chelated by the carboxylate group. The geometry is a distorted N(4)O(2) octahedron. In the crystal, adjacent molecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into a zigzag chain parallel to [010]. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414150/ /pubmed/22904757 http://dx.doi.org/10.1107/S1600536812032175 Text en © Gao and Cao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Qiang Cao, Yi-Cheng (Cinnamato-κ(2) O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title | (Cinnamato-κ(2)
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full | (Cinnamato-κ(2)
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_fullStr | (Cinnamato-κ(2)
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full_unstemmed | (Cinnamato-κ(2)
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_short | (Cinnamato-κ(2)
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_sort | (cinnamato-κ(2)
o,o′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
n,n′,n′′,n′′′)nickel(ii) perchlorate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414150/ https://www.ncbi.nlm.nih.gov/pubmed/22904757 http://dx.doi.org/10.1107/S1600536812032175 |
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