(Ethano­lato-κO)[N′-(3-meth­oxy-2-oxidobenzyl­idene-κO (2))benzo­hydrazidato-κ(2) N′,O]oxidovanadium(V)

In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano­late anion and two O atoms and one N atom from the tridentate benzo­hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basa...

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Detalles Bibliográficos
Autores principales: Chen, Xiao-Hua, Wu, Qiong-Jie, Chen, Li-Juan, Yang, Ming-Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414151/
https://www.ncbi.nlm.nih.gov/pubmed/22904758
http://dx.doi.org/10.1107/S1600536812032229
Descripción
Sumario:In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethano­late anion and two O atoms and one N atom from the tridentate benzo­hydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intra­molecular O—H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal.

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