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(Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) N′,O]oxidovanadium(V)
In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basa...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414151/ https://www.ncbi.nlm.nih.gov/pubmed/22904758 http://dx.doi.org/10.1107/S1600536812032229 |
| _version_ | 1782240162485370880 |
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| author | Chen, Xiao-Hua Wu, Qiong-Jie Chen, Li-Juan Yang, Ming-Xing |
| author_facet | Chen, Xiao-Hua Wu, Qiong-Jie Chen, Li-Juan Yang, Ming-Xing |
| author_sort | Chen, Xiao-Hua |
| collection | PubMed |
| description | In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intramolecular O—H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak intermolecular C—H⋯O hydrogen bonding is present in the crystal. |
| format | Online Article Text |
| id | pubmed-3414151 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141512012-08-17 (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) N′,O]oxidovanadium(V) Chen, Xiao-Hua Wu, Qiong-Jie Chen, Li-Juan Yang, Ming-Xing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [V(C(15)H(12)N(2)O(4))(C(2)H(5)O)O], the V(V) ion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intramolecular O—H⋯N hydrogen bond occurs in the benzohydrazidate ligand. Weak intermolecular C—H⋯O hydrogen bonding is present in the crystal. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414151/ /pubmed/22904758 http://dx.doi.org/10.1107/S1600536812032229 Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Xiao-Hua Wu, Qiong-Jie Chen, Li-Juan Yang, Ming-Xing (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))benzohydrazidato-κ(2) N′,O]oxidovanadium(V) |
| title | (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
| title_full | (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
| title_fullStr | (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
| title_full_unstemmed | (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
| title_short | (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))benzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
| title_sort | (ethanolato-κo)[n′-(3-methoxy-2-oxidobenzylidene-κo
(2))benzohydrazidato-κ(2)
n′,o]oxidovanadium(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414151/ https://www.ncbi.nlm.nih.gov/pubmed/22904758 http://dx.doi.org/10.1107/S1600536812032229 |
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