cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate

In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N—Pd—Cl angles of 172.63 (8) an...

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Detalles Bibliográficos
Autores principales: Obuah, Collins, Darkwa, James, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414152/
https://www.ncbi.nlm.nih.gov/pubmed/22904759
http://dx.doi.org/10.1107/S1600536812032308
Descripción
Sumario:In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N—Pd—Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N—H⋯Cl hydrogen bonds creating infinite chains along [001], several C—H⋯Cl inter­actions are observed in the crystal structure.

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