cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate

In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N—Pd—Cl angles of 172.63 (8) an...

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Detalles Bibliográficos
Autores principales: Obuah, Collins, Darkwa, James, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414152/
https://www.ncbi.nlm.nih.gov/pubmed/22904759
http://dx.doi.org/10.1107/S1600536812032308
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author Obuah, Collins
Darkwa, James
Muller, Alfred
author_facet Obuah, Collins
Darkwa, James
Muller, Alfred
author_sort Obuah, Collins
collection PubMed
description In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N—Pd—Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N—H⋯Cl hydrogen bonds creating infinite chains along [001], several C—H⋯Cl inter­actions are observed in the crystal structure.
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spelling pubmed-34141522012-08-17 cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate Obuah, Collins Darkwa, James Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(7)H(13)N(3))]·CH(2)Cl(2), the 2-(3,5-dimethyl-1H-pyrazol-1-yl)ethanamine ligand chelates the Pd(II) atom via two N atoms forming a six-membered ring resulting in a distorted square-planar metal coordination environment, highlighted by N—Pd—Cl angles of 172.63 (8) and 174.98 (9)°. In addition to N—H⋯Cl hydrogen bonds creating infinite chains along [001], several C—H⋯Cl inter­actions are observed in the crystal structure. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414152/ /pubmed/22904759 http://dx.doi.org/10.1107/S1600536812032308 Text en © Obuah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Obuah, Collins
Darkwa, James
Muller, Alfred
cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title_full cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title_fullStr cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title_full_unstemmed cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title_short cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]palladium(II) dichloro­methane monosolvate
title_sort cis-dichlorido[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))ethanamine-κn]palladium(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414152/
https://www.ncbi.nlm.nih.gov/pubmed/22904759
http://dx.doi.org/10.1107/S1600536812032308
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AT mulleralfred cisdichlorido235dimethyl1hpyrazol1ylkn2ethanamineknpalladiumiidichloromethanemonosolvate

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