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Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)

The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol mol­ecules. In the asymmetric unit, there are two half mol­ecules, with the Co(II) atoms located on inversion centre...

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Detalles Bibliográficos
Autores principales: Idemudia, Omoruyi G., Hosten, Eric C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414155/
https://www.ncbi.nlm.nih.gov/pubmed/22904762
http://dx.doi.org/10.1107/S1600536812032837
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author Idemudia, Omoruyi G.
Hosten, Eric C.
author_facet Idemudia, Omoruyi G.
Hosten, Eric C.
author_sort Idemudia, Omoruyi G.
collection PubMed
description The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol mol­ecules. In the asymmetric unit, there are two half mol­ecules, with the Co(II) atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the ethanol is disordered over two sets of sites [occupancy ratio 0.757 (7):0.243 (7)]. Each BMPP ligand is deprotonated with the negative charge delocalized. The hy­droxy group of each ethanol mol­ecule forms hydrogen bonds with a pyrazole N atom in an adjacent BMPP ligand. Weaker C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a three-dimensional structure.
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spelling pubmed-34141552012-08-17 Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II) Idemudia, Omoruyi G. Hosten, Eric C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol mol­ecules. In the asymmetric unit, there are two half mol­ecules, with the Co(II) atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the ethanol is disordered over two sets of sites [occupancy ratio 0.757 (7):0.243 (7)]. Each BMPP ligand is deprotonated with the negative charge delocalized. The hy­droxy group of each ethanol mol­ecule forms hydrogen bonds with a pyrazole N atom in an adjacent BMPP ligand. Weaker C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a three-dimensional structure. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414155/ /pubmed/22904762 http://dx.doi.org/10.1107/S1600536812032837 Text en © Idemudia and Hosten 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Idemudia, Omoruyi G.
Hosten, Eric C.
Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title_full Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title_fullStr Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title_full_unstemmed Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title_short Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(ethanol-κO)cobalt(II)
title_sort bis(4-benzoyl-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2) o,o′)bis­(ethanol-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414155/
https://www.ncbi.nlm.nih.gov/pubmed/22904762
http://dx.doi.org/10.1107/S1600536812032837
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