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Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis(ethanol-κO)cobalt(II)
The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol molecules. In the asymmetric unit, there are two half molecules, with the Co(II) atoms located on inversion centre...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414155/ https://www.ncbi.nlm.nih.gov/pubmed/22904762 http://dx.doi.org/10.1107/S1600536812032837 |
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author | Idemudia, Omoruyi G. Hosten, Eric C. |
author_facet | Idemudia, Omoruyi G. Hosten, Eric C. |
author_sort | Idemudia, Omoruyi G. |
collection | PubMed |
description | The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol molecules. In the asymmetric unit, there are two half molecules, with the Co(II) atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the ethanol is disordered over two sets of sites [occupancy ratio 0.757 (7):0.243 (7)]. Each BMPP ligand is deprotonated with the negative charge delocalized. The hydroxy group of each ethanol molecule forms hydrogen bonds with a pyrazole N atom in an adjacent BMPP ligand. Weaker C—H⋯O and C—H⋯N interactions link the molecules into a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3414155 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141552012-08-17 Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis(ethanol-κO)cobalt(II) Idemudia, Omoruyi G. Hosten, Eric C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol molecules. In the asymmetric unit, there are two half molecules, with the Co(II) atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the ethanol is disordered over two sets of sites [occupancy ratio 0.757 (7):0.243 (7)]. Each BMPP ligand is deprotonated with the negative charge delocalized. The hydroxy group of each ethanol molecule forms hydrogen bonds with a pyrazole N atom in an adjacent BMPP ligand. Weaker C—H⋯O and C—H⋯N interactions link the molecules into a three-dimensional structure. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414155/ /pubmed/22904762 http://dx.doi.org/10.1107/S1600536812032837 Text en © Idemudia and Hosten 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Idemudia, Omoruyi G. Hosten, Eric C. Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis(ethanol-κO)cobalt(II) |
title | Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,O′)bis(ethanol-κO)cobalt(II) |
title_full | Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,O′)bis(ethanol-κO)cobalt(II) |
title_fullStr | Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,O′)bis(ethanol-κO)cobalt(II) |
title_full_unstemmed | Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,O′)bis(ethanol-κO)cobalt(II) |
title_short | Bis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2)
O,O′)bis(ethanol-κO)cobalt(II) |
title_sort | bis(4-benzoyl-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2)
o,o′)bis(ethanol-κo)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414155/ https://www.ncbi.nlm.nih.gov/pubmed/22904762 http://dx.doi.org/10.1107/S1600536812032837 |
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