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Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized molecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octa...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414156/ https://www.ncbi.nlm.nih.gov/pubmed/22904763 http://dx.doi.org/10.1107/S1600536812029856 |
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author | Liu, Wei Li, Xia |
author_facet | Liu, Wei Li, Xia |
author_sort | Liu, Wei |
collection | PubMed |
description | In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized molecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octahedral geometry, ligated by two N atoms and two O atoms from a 2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylate) dianion, one N atom from a pyridine molecule and one coordinating water molecule. The Co—O bond lengths range from 2.076 (2) to 2.1441 (15) Å, while the Co—N bond lengths are 2.138 (3) and 2.1515 (17) Å. A two-dimensional network of N—H⋯O and O—H⋯N hydrogen bonds stabilizes the crystal packing. There are π–π interactions between the bipyridine and imidazole rings [centroid–centroid distance = 3.7694 (4) Å]. The propane-1,3-diyl group is disordered over two conformations, with refined occupancies of 0.755 (8) and 0.245 (8). |
format | Online Article Text |
id | pubmed-3414156 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141562012-08-17 Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) Liu, Wei Li, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized molecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octahedral geometry, ligated by two N atoms and two O atoms from a 2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylate) dianion, one N atom from a pyridine molecule and one coordinating water molecule. The Co—O bond lengths range from 2.076 (2) to 2.1441 (15) Å, while the Co—N bond lengths are 2.138 (3) and 2.1515 (17) Å. A two-dimensional network of N—H⋯O and O—H⋯N hydrogen bonds stabilizes the crystal packing. There are π–π interactions between the bipyridine and imidazole rings [centroid–centroid distance = 3.7694 (4) Å]. The propane-1,3-diyl group is disordered over two conformations, with refined occupancies of 0.755 (8) and 0.245 (8). International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414156/ /pubmed/22904763 http://dx.doi.org/10.1107/S1600536812029856 Text en © Liu and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Wei Li, Xia Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title | Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4)
N
(3),O
(4):N
(3′),O
(4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title_full | Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4)
N
(3),O
(4):N
(3′),O
(4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title_fullStr | Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4)
N
(3),O
(4):N
(3′),O
(4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title_full_unstemmed | Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4)
N
(3),O
(4):N
(3′),O
(4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title_short | Aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1H-imidazole-4-carboxylato)-κ(4)
N
(3),O
(4):N
(3′),O
(4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) |
title_sort | aqua[2,2′-(propane-1,3-diyl)bis(5-carboxy-1h-imidazole-4-carboxylato)-κ(4)
n
(3),o
(4):n
(3′),o
(4′)](pyridine-κn)cobalt(ii)–4,4′-bipyridine (1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414156/ https://www.ncbi.nlm.nih.gov/pubmed/22904763 http://dx.doi.org/10.1107/S1600536812029856 |
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