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Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)

In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized mol­ecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octa­...

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Detalles Bibliográficos
Autores principales: Liu, Wei, Li, Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414156/
https://www.ncbi.nlm.nih.gov/pubmed/22904763
http://dx.doi.org/10.1107/S1600536812029856
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author Liu, Wei
Li, Xia
author_facet Liu, Wei
Li, Xia
author_sort Liu, Wei
collection PubMed
description In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized mol­ecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octa­hedral geometry, ligated by two N atoms and two O atoms from a 2,2′-(propane-1,3-di­yl)bis­(5-carboxy-1H-imidazole-4-carboxyl­ate) dianion, one N atom from a pyridine mol­ecule and one coordinating water mol­ecule. The Co—O bond lengths range from 2.076 (2) to 2.1441 (15) Å, while the Co—N bond lengths are 2.138 (3) and 2.1515 (17) Å. A two-dimensional network of N—H⋯O and O—H⋯N hydrogen bonds stabilizes the crystal packing. There are π–π inter­actions between the bipyridine and imidazole rings [centroid–centroid distance = 3.7694 (4) Å]. The propane-1,3-diyl group is disordered over two conformations, with refined occupancies of 0.755 (8) and 0.245 (8).
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spelling pubmed-34141562012-08-17 Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1) Liu, Wei Li, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(10)N(4)O(8))(C(5)H(5)N)(H(2)O)]·C(10)H(8)N(2), the asymmetric unit comprises half a Co(II) complex located on a mirror plane and half a cocrystallized mol­ecule of 4,4′-bipyridine located on an inversion center. The Co(II) ion is six coordinate, with distorted octa­hedral geometry, ligated by two N atoms and two O atoms from a 2,2′-(propane-1,3-di­yl)bis­(5-carboxy-1H-imidazole-4-carboxyl­ate) dianion, one N atom from a pyridine mol­ecule and one coordinating water mol­ecule. The Co—O bond lengths range from 2.076 (2) to 2.1441 (15) Å, while the Co—N bond lengths are 2.138 (3) and 2.1515 (17) Å. A two-dimensional network of N—H⋯O and O—H⋯N hydrogen bonds stabilizes the crystal packing. There are π–π inter­actions between the bipyridine and imidazole rings [centroid–centroid distance = 3.7694 (4) Å]. The propane-1,3-diyl group is disordered over two conformations, with refined occupancies of 0.755 (8) and 0.245 (8). International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414156/ /pubmed/22904763 http://dx.doi.org/10.1107/S1600536812029856 Text en © Liu and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Wei
Li, Xia
Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title_full Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title_fullStr Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title_full_unstemmed Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title_short Aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1H-imidazole-4-carboxyl­ato)-κ(4) N (3),O (4):N (3′),O (4′)](pyridine-κN)cobalt(II)–4,4′-bipyridine (1/1)
title_sort aqua­[2,2′-(propane-1,3-di­yl)bis­(5-car­boxy-1h-imidazole-4-carboxyl­ato)-κ(4) n (3),o (4):n (3′),o (4′)](pyridine-κn)cobalt(ii)–4,4′-bipyridine (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414156/
https://www.ncbi.nlm.nih.gov/pubmed/22904763
http://dx.doi.org/10.1107/S1600536812029856
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