Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate

The crystal structure of the title complex, [Ni(C(12)H(28)N(4))(H(2)O)(2)]Cl(2)·2H(2)O, displays O—H⋯Cl and O—H⋯O hydrogen bonding. The tetra­aza­cyclo­tetra­decane ligand inter­acts with the Ni(II) atom in the cis V configuration and the final two ligand binding sites are occupied by water....

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Detalles Bibliográficos
Autores principales: Townsend, James Alan, Desper, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414157/
https://www.ncbi.nlm.nih.gov/pubmed/22904764
http://dx.doi.org/10.1107/S160053681203276X
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author Townsend, James Alan
Desper, John
author_facet Townsend, James Alan
Desper, John
author_sort Townsend, James Alan
collection PubMed
description The crystal structure of the title complex, [Ni(C(12)H(28)N(4))(H(2)O)(2)]Cl(2)·2H(2)O, displays O—H⋯Cl and O—H⋯O hydrogen bonding. The tetra­aza­cyclo­tetra­decane ligand inter­acts with the Ni(II) atom in the cis V configuration and the final two ligand binding sites are occupied by water.
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spelling pubmed-34141572012-08-17 Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate Townsend, James Alan Desper, John Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Ni(C(12)H(28)N(4))(H(2)O)(2)]Cl(2)·2H(2)O, displays O—H⋯Cl and O—H⋯O hydrogen bonding. The tetra­aza­cyclo­tetra­decane ligand inter­acts with the Ni(II) atom in the cis V configuration and the final two ligand binding sites are occupied by water. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414157/ /pubmed/22904764 http://dx.doi.org/10.1107/S160053681203276X Text en © Townsend and Desper 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Townsend, James Alan
Desper, John
Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title_full Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title_fullStr Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title_full_unstemmed Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title_short Diaqua­[(1R,2S,4R,8R,9S,11R)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(II) dichloride dihydrate
title_sort diaqua­[(1r,2s,4r,8r,9s,11r)-2,9-di­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane]nickel(ii) dichloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414157/
https://www.ncbi.nlm.nih.gov/pubmed/22904764
http://dx.doi.org/10.1107/S160053681203276X
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AT desperjohn diaqua1r2s4r8r9s11r29dimethyl14811tetraazacyclotetradecanenickeliidichloridedihydrate

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